JEE Main 2026 April 5 Shift 1 chemistry question paper is available here with answer key and solutions. NTA conducted the second shift of the day on April 5, 2026, from 9:00 AM to 12:00 PM.

  • The JEE Main Chemistry Question Paper contains a total of 25 questions.
  • Each correct answer gets you 4 marks while incorrect answers gets you a negative mark of 1.

Candidates can download the JEE Main 2026 April 5 Shift 1 chemistry question paper along with detailed solutions to analyze their performance and understand the exam pattern better.

JEE Main 2026 April 5 Shift 1 Chemistry Question Paper with Solution PDF

JEE Mains 2026 April 5 Shift 1 Chemistry Question Paper with Solutions

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Question 1:

How many grams of residue is obtained by heating \(2.76 g\) of silver carbonate? (Given : Molar mass of C, O and Ag are 12, 16 and \(108 g mol^{-1}\) respectively)

  • (A) \(1.08 g\)
  • (B) \(2.16 g\)
  • (C) \(3.24 g\)
  • (D) \(4.32 g\)

Question 2:

Arrange the following atomic orbitals of multi electron atoms in order of increasing energy.

A. \(n=3, l=2, m=+1\)

B. \(n=4, l=0, m=0\)

C. \(n=6, l=1, m=0\)

D. \(n=5, l=1, m=+1\)

E. \(n=2, l=1, m=+1\)

  • (A) \(C < D < B < A < E\)
  • (B) \(B < A < E < C < D\)
  • (C) \(E < C < D < B < A\)
  • (D) \(E < B < A < D < C\)

Question 3:

Identify the correct statements from the following :

A. Heisenberg uncertainty principle is applicable to electrons.

B. The size of \(2p_x\) orbital is less than the size of \(3p_x\) orbital.

C. The energy of \(2s\) orbital of H atom is equal to the energy of \(2s\) orbital of Li.

D. The electronic configuration of Cr is \([Ar] 3d^5 4s^1\)

  • (A) A, B and C Only
  • (B) A, B and D Only
  • (C) B, C and D Only
  • (D) A, C and D Only

Question 4:

What is the mole fraction of water in \(10%\) by weight (w/w) of aqueous urea solution? [Given: Molar mass of H, O, C and N are 1, 16, 12 and \(14 g mol^{-1}\) respectively.]

  • (A) 0.825
  • (B) 0.032
  • (C) 0.867
  • (D) 0.967

Question 5:

\(M_3A_2\) is a sparingly soluble salt of molar mass \(y g mol^{-1}\) and solubility \(x g L^{-1}\). The ratio of the molar concentration of the anion (\(A^{3-}\)) to the solubility product (\(K_{sp}\)) of the salt is:

  • (A) \(\frac{1}{54} \frac{y^4}{x^4}\)
  • (B) \(\frac{y^5}{108x^4}\)
  • (C) \(108 \frac{x^5}{y^5}\)
  • (D) \(\frac{1}{108}\frac{y^4}{x^4}\)

Question 6:

Arrange the following resultant mixtures in increasing order of their pH values

A. \(10 mL 0.2 M Ca(OH)_2 + 25 mL 0.1 M HCl\)

B. \(10 mL 0.01 M H_2SO_4 + 10 mL 0.01 M Ca(OH)_2\)

C. \(10 mL 0.1 M H_2SO_4 + 10 mL 0.1 M KOH\)

  • (A) B \(<\) C \(<\) A
  • (B) C \(<\) A \(<\) B
  • (C) C \(<\) B \(<\) A
  • (D) A \(<\) C \(<\) B

Question 7:

First order gas phase reaction \(A \to B + C\). \(p_i = initial pressure of gas A\), \(P_t = total pressure of the reaction mixture at time t\). Expression of rate constant (k) is

  • (A) \(\frac{1}{t} \ln \frac{p_i}{2p_i - P_t}\)
  • (B) \(\frac{1}{t} \ln \frac{2p_i}{p_i - P_t}\)
  • (C) \(\frac{1}{t} \ln \frac{p_i}{3p_i - 2P_t}\)
  • (D) \(\frac{1}{t} \ln \frac{3p_i}{4p_i - P_t}\)

Question 8:

Given below are two statements:

Statement I: The correct order of electronegativity of fluorine, oxygen and nitrogen is \(F > O > N\).

Statement II: The oxidation state of oxygen in \(OF_2\) is \(+2\) and in \(Na_2O\) is \(-2\).

  • (A) Both Statement I and Statement II are true
  • (B) Both Statement I and Statement II are false
  • (C) Statement I is true but Statement II is false
  • (D) Statement I is false but Statement II is true

Question 9:

Correct statements from the following are:

A. Nitrogen in oxidation states from \(+1\) to \(+4\) disproportionates in acid medium.

B. Nitrogen has the ability to form \(d\pi - p\pi\) multiple bonds with itself and other elements with small size and high electronegativity.

C. N-N single bond is stronger than P-P single bond.

D. Nitrogen has highest density in its group due to small size.

E. The maximum covalency of nitrogen is four since it has only four valence orbitals for bonding.

  • (A) B, C and D Only
  • (B) C, D and E Only
  • (C) A, C and E Only
  • (D) A and E Only

Question 10:

Which of the following is NOT a physical or chemical characteristic of interstitial compounds?

  • (A) They have high melting points, higher than those of pure metals.
  • (B) They are very soft and ionic in nature.
  • (C) They retain metallic conductivity.
  • (D) They are chemically inert and usually non-stoichiometric.

Question 11:

The correct statements about metal carbonyls are:

A. The metal-carbon bonds in metal carbonyls possess both \(\sigma\) and \(\pi\) character.

B. Due to synergic bonding interactions between metal and CO ligand, the metal-carbon bond becomes weak.

C. The metal-carbon \(\sigma\) bond is formed by the donation of lone pair of electrons on the carbonyl carbon into a vacant orbital of metal.

D. The metal-carbon \(\pi\) bond is formed by the donation of electrons from filled d-orbital of metal into vacant \(\pi^*\) orbital of CO.

  • (A) A and B Only
  • (B) A, C and D Only
  • (C) B and C Only
  • (D) A and D Only

Question 12:

Given below are two statements:

Statement I: Each electron in \(e_g\) orbitals destabilizes the orbitals by \(+0.6 \Delta_o\) and each electron in the \(t_{2g}\) orbitals stabilizes the orbitals by \(-0.4 \Delta_o\) in an octahedral field on the basis of crystal field theory.

Statement II: All the d-orbitals of the transition metals have the same energy in their free atomic state but when a complex is formed the ligands destroy the degeneracy of these orbitals on the basis of crystal field theory.

  • (A) Both Statement I and Statement II are correct
  • (B) Both Statement I and Statement II are incorrect
  • (C) Statement I is correct but Statement II is incorrect
  • (D) Statement I is incorrect but Statement II is correct

Question 13:

Given below are two statements:

Statement I: On the basis of inductive effect, the order of stability of alkyl carbanions is \(CH_3^- > CH_3-CH_2^- > (CH_3)_2CH^- > (CH_3)_3C^-\).

Statement II: Allyl and benzyl carbanions are more stabilised by inductive effect and not by resonance effect.

  • (A) Both Statement I and Statement II are correct
  • (B) Both Statement I and Statement II are incorrect
  • (C) Statement I is correct but Statement II is incorrect
  • (D) Statement I is incorrect but Statement II is correct

Question 14:

"P" is a hydrocarbon of molecular formula:- \(C_8H_{14}\). On ozonolysis, "P" forms "Q". "Q" on treatment with alkali under reflux condition produces "R", which on treatment with \(I_2 / NaOH\) gives a yellow precipitate. Acidification of the solution gives "S". The structure of "S" is given below:-




The correct structure of "P" is

  • (A)
  • (B)
  • (C)
  • (D)

Question 15:

For the following Friedel Craft's alkylation reaction, which of the statements are correct?



A. Major product is n-propyl benzene.

B. iso-propyl carbocation intermediate is also generated.

C. Multiple substitution is inevitable.

D. Introducing electron-donating substituent on benzene will not produce any alkyl benzene.

  • (A) A and D only
  • (B) B and C only
  • (C) A and C only
  • (D) B and D only

Question 16:

Benzyl isocyanide can be obtained from

  • (A) A and B Only
  • (B) A and C Only
  • (C) B and D Only
  • (D) D and E Only

Question 17:

Consider compounds A, B and C with following structural formulae
\(A = CH_3 - CH_2 - CH_2 - CH_2 - CH_2 - OH\)
\(B = CH_2 = CH - CH_2 - CH_2 - CH_3\)
\(C = HO - CH_2 - CH_2 - CH(OH) - CH_3\)

For the conversion of B from A, reagent (D) required is ____ and structural formula of product (E) obtained when C undergoes same reaction using excess reagent (D) is ____.

  • (A)
  • (B)
  • (C)
  • (D)

Question 18:

Identify the incorrect statements.

  • (A) A and D Only
  • (B) A and C Only
  • (C) B and C Only
  • (D) A and B Only

Question 19:

Identify the correct statements.

A. Glucose exists in two anomeric forms.

B. Anomers of glucose differ in configuration at C-1 in cyclic hemiacetal structure.

C. Melting point of \(\alpha\)-anomer of glucose is greater than \(\beta\)-anomer.

D. Specific rotation of \(\alpha\)-anomer is \(+19^\circ\) while for \(\beta\)-anomer is \(+112^\circ\).

E. \(\alpha\) and \(\beta\) anomers of glucose are prepared by crystallization of saturated glucose solution at \(303 K\) and \(371 K\) respectively.

  • (A) A and B Only
  • (B) B and C Only
  • (C) A, B and D Only
  • (D) A, B and E Only

Question 20:

Given below are two statements:

Statement I: Sodium dichromate and potassium dichromate are classified as primary standards in titrimetric analysis.

Statement II: Phenolphthalein is a weak base, therefore it dissociates in acidic medium.

  • (A) Both Statement I and Statement II are true
  • (B) Both Statement I and Statement II are false
  • (C) Statement I is true but Statement II is false
  • (D) Statement I is false but Statement II is true

Question 21:

Consider the following species:
\(BrF_5, XeF_5^-, BF_4^-, ICl_4^-, XeF_4, SF_4, NH_4^+, ClF_3, XeF_2, ICl_2^-\)

Number of species having \(sp^3d\) hybridized central atom is ____.


Question 22:

In an estimation of sulphur by Carius method \(0.2 g\) of the substance gave \(0.6 g\) of \(BaSO_4\). The percentage of sulphur in the substance is ____ %.
(Given molar mass in \(g mol^{-1}\) S : 32, \(BaSO_4 : 231\))


Question 23:

One mole of phenol is treated with dilute \(HNO_3\) at \(298 K\) to give a mixture of products. The mixture is separated by steam distillation. The steam volatile compound (X) is separated. The increase in percentage of oxygen in (X) with respect to phenol is ____ \(\times 10^{-1}\) %.
(Given molar mass in \(g mol^{-1}\) H:1, C:12, N:14, O:16)


Question 24:

The values of pressure equilibrium constant recorded at different temperatures for the following equilibrium reaction have been given below:
\(A(g) \rightleftharpoons B(g) + C(g)\)



The magnitude of \(\frac{\Delta H^\circ}{R}\) calculated from the above data is ____. (Nearest integer)


Question 25:

If the half life of a first order reaction is \(6.93 minutes\) then the time required for completion of \(99 %\) of the reaction will be ____ minutes.
(Given : \(\log 2 = 0.3010\))

JEE Main 2026 Chemistry Exam Pattern

Particulars Details
Exam Mode Online (Computer-Based Test)
Paper B.E./B.Tech
Medium of Exam 13 languages: English, Hindi, Gujarati, Bengali, Tamil, Telugu, Kannada, Marathi, Malayalam, Odia, Punjabi, Assamese, Urdu
Type of Questions Multiple Choice Questions (MCQs) + Numerical Value Questions
Total Marks 100 marks
Marking Scheme +4 for correct answer & -1 for incorrect MCQ and Numerical Value-based Questions
Total Questions 25 Questions

JEE Main 2026 Chemistry Revision