JEE Main 2025 April 4 Shift 2 Chemistry Question Paper, Exam Analysis, and Answer Keys (Available)

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Shivam Yadav

Updated on - Nov 26, 2025

JEE Main 2025 April 4 Chemistry Question Paper is available for download. NTA conducted JEE Main 2025 Shift 1 B.Tech Exam on 3rd April 2025 from 9:00 AM to 12:00 PM and for JEE Main 2025 B.Tech Shift 2 appearing candidates from 3:00 PM to 6:00 PM. The JEE Main 2025 3rd April B.Tech Question Paper was Moderate to Tough.

Also Check: JEE Main 2025 Question Paper with Solution PDF Download

JEE Main 2025 April 4 Shift 2 Chemistry Question Paper with Solutions

JEE Main 2025 April 4 Shift 2 Chemistry Question Paper Pdf Download PDF View Solution
jee main april 4

Question 1:

The correct order of basicity for the following molecules is:

image

  • (1) \( P > Q > R \)
  • (2) \( R > P > Q \)
  • (3) \( Q > P > R \)
  • (4) \( R > Q > P \)

Question 2:

The incorrect relationship in the following pairs in relation to ionisation enthalpies is:

  • (1) \( Mn^{2+} < Cr^{3+} \)
  • (2) \( Mn^{2+} < Mn^{3+} \)
  • (3) \( Fe^{2+} < Fe^{3+} \)
  • (4) \( Fe^{2+} < Fe^{3+} \)

Question 3:

Which among the following compounds give yellow solid when reacted with NaOI/NaOH?
image

Choose the correct answer from the options given below:

  • (1) (B), (C) and (E) Only
  • (2) (A) and (C) Only
  • (3) (C) and (D) Only
  • (4) (A), (C) and (D) Only

Question 4:

A dipeptide, “x”, on complete hydrolysis gives “y” and “z”; “y” on treatment with aqueous HNO\(_2\), produces lactic acid. On the other hand, “z” on heating gives the following cyclic molecule.

image

Based on the information given, the dipeptide X is:

  • (1) valine-glycine
  • (2) alanine-glycine
  • (3) valine-leucine
  • (4) alanine-alanine

Question 5:

In which pairs, the first ion is more stable than the second?

image

  • (1) (B) \& (D) only
  • (2) (A) \& (B) only
  • (3) (B) \& (C) only
  • (4) (A) \& (C) only

Question 6:

Given below are two statements:

Statement (I): Alcohols are formed when alkyl chlorides are treated with aqueous potassium hydroxide by elimination reaction.

Statement (II): In alcoholic potassium hydroxide, alkyl chlorides form alkenes by abstracting the hydrogen from the \( \beta \)-carbon.

In the light of the above statements, choose the most appropriate answer from the options given below:

  • (1) Both Statement I and Statement II are incorrect
  • (2) Statement I is incorrect but Statement II is correct
  • (3) Statement I is correct but Statement II is incorrect
  • (4) Both Statement I and Statement II are correct

Question 7:

Given below are two statements:

Statement (I): Molal depression constant \( k_f \) is given by \( \frac{M_1 R T_f}{\Delta S_{fus}} \), where symbols have their usual meaning.
Statement (II): \( k_f \) for benzene is less than the \( k_f \) for water.


In light of the above statements, choose the most appropriate answer from the options given below:

  • (1) Statement I is incorrect but Statement II is correct
  • (2) Both Statement I and Statement II are incorrect
  • (3) Both Statement I and Statement II are correct
  • (4) Statement I is correct but Statement II is incorrect

Question 8:

The IUPAC name of the following compound is:
image

  • (1) 4-Hydroxyhept-1-en-6-yne
  • (2) 4-Hydroxyhept-6-en-1-yne
  • (3) Hept-6-en-1-yn-4-ol
  • (4) Hept-1-en-6-yn-4-ol

Question 9:

Match List-I with List-II:

List-I                                                                                            List-II

  • (A) Aniline from aniline-water mixture                                      (I) Simple distillation
  • (B) Glycerol from spent-lye in soap industry                          (II) Fractional distillation
  • (C) Different fractions of crude oil in petroleum industry       (III) Distillation at reduced pressure
  • (D) Chloroform-Aniline mixture                                              (IV) Steam distillation
  • Choose the correct answer from the options given below:
  • (1) (A)-(IV), (B)-(III), (C)-(II), (D)-(I)
  • (2) (A)-(I), (B)-(II), (C)-(III), (D)-(IV)
  • (3) (A)-(III), (B)-(II), (C)-(I), (D)-(IV)
  • (4) (A)-(II), (B)-(I), (C)-(IV), (D)-(III)

Question 10:

A toxic compound “A” when reacted with NaCN in aqueous acidic medium yields an edible cooking component and food preservative “B”. “B” is converted to “C” by dibromane and can be used as an additive to petrol to reduce emission. “C” upon reaction with oleum at 140°C yields an inhalable anesthetic “D”. Identify “A”, “B”, “C”, and “D”, respectively.

  • (1) Methanol; formaldehyde; methyl chloride; chloroform
  • (2) Ethanol; acetonitrile; ethylamine; ethylene
  • (3) Methanol; acetic acid; ethanol; diethyl ether
  • (4) Acetaldehyde; 2-hydroxyethane; acetic acid; propanoic acid

Question 11:

The correct order of \( [FeF_6]^{3-} \), \( [CoF_6]^{3-} \),\( [Ni(CO)_4] \) and \( [Ni(CN)_4]^{2-} \) complex species based on the number of unpaired electrons present is:
 

  • (1) \( [FeF_6]^{3-} > [CoF_6]^{3-} > [Ni(CN)_4]^{2-} > [Ni(CO)_4] \)
  • (2) \( [Ni(CN)_4]^{2-} > [FeF_6]^{3-} > [CoF_6]^{3-} > [Ni(CO)_4] \)
  • (3) \( [CoF_6]^{3-} > [FeF_6]^{3-} > [Ni(CO)_4] > [Ni(CN)_4]^{2-} \)
  • (4) \( [FeF_6]^{3-} > [CoF_6]^{3-} > [Ni(CN)_4]^{2-} = [Ni(CO)_4] \)

Question 12:

Consider the given data:
\[ (a) HCl(g) + 10H_2O(l) \rightarrow HCl.10 H_2O \quad \Delta H = -69.01 \, kJ/mol^{-1} \]
\[ (b) HCl(g) + 40H_2O(l) \rightarrow HCl.40 H_2O \quad \Delta H = -72.79 \, kJ/mol^{-1} \]

Choose the correct statement:

  • (1) Dissolution of gas in water is an endothermic process
  • (2) The heat of solution depends on the amount of solvent
  • (3) The heat of dilution for the HCl (HCl.10H\(_2\)O to HCl.40H\(_2\)O) is 3.78 kJ/mol
  • (4) The heat of formation of HCl solution is represented by both (a) and (b)

Question 13:

Consider the ground state of an atom (Z = 24). How many electrons are arranged with Azimuthal quantum number \( l = 1 \) and \( l = 2 \) respectively?

  • (1) 12 and 4
  • (2) 16 and 4
  • (3) 12 and 5
  • (4) 12 and 5 and 6

Question 14:

Given below are two statements:


Statement (I): The first ionisation enthalpy of group 14 elements is higher than the corresponding elements of group 13.

Statement (II): Melting points and boiling points of group 13 elements are in general much higher than those of the corresponding elements of group 14.

Choose the most appropriate answer from the options given below:

  • (1) Statement I is correct but Statement II is incorrect
  • (2) Statement I is incorrect but Statement II is correct
  • (3) Both Statement I and Statement II are incorrect
  • (4) Both Statement I and Statement II are correct

Question 15:

Consider the following plots of log of rate constant \( k (log k)\) vs \( \frac{1}{T} \) for three different reactions. The correct order of activation energies of these reactions is:

image

Choose the correct answer from the options given below:

 

  • (1) \( Ea_2 > Ea_1 > Ea_3 \)
  • (2) \( Ea_1 > Ea_3 > Ea_2 \)
  • (3) \( Ea_1 > Ea_2 > Ea_3 \)
  • (4) \( Ea_3 > Ea_2 > Ea_1 \)

Question 16:

‘X’ is the number of electrons in \( t_2g \) orbitals of the most stable complex ion among \( [Fe(NH_3)_6]^{3+} \), \( [Fe(Cl)_6]^{3-} \), \( [Fe(C_2O_4)_3]^{3-} \) and \( [Fe(H_2O)_6]^{3+} \).

The nature of oxide of vanadium of the type \( V_2O_x \) is:

 

  • (1) Acidic
  • (2) Neutral
  • (3) Basic
  • (4) Amphoteric

Question 17:

The elements of Group 13 with highest and lowest first ionisation enthalpies are respectively:
 

  • (1) B \& Ga
  • (2) B \& Tl
  • (3) Ti \& B
  • (4) B \& In

Question 18:

Consider the following molecule (X).

image

The structure of \( X \) is:

image


Question 19:

Given below are two statements:

image
Statement (II): Structure III is most stable, as the orbitals having the lone pairs are axial, where the \( \ell p - \beta p \) repulsion is minimum.

In light of the above statements, choose the most appropriate answer from the options given below:

  • (1) Statement I is incorrect but Statement II is correct
  • (2) Statement I is correct but Statement II is incorrect
  • (3) Both Statement I and Statement II are correct
  • (4) Both Statement I and Statement II are incorrect

Question 20:

Half-life of zero-order reaction \( A \to \) product is 1 hour, when initial concentration of reaction is 2.0 mol L\(^{-1}\). The time required to decrease concentration of A from 0.50 to 0.25 mol L\(^{-1}\) is:

  • (1) 0.5 hour
  • (2) 4 hour
  • (3) 15 min
  • (4) 60 min

Question 21:

Sea water, which can be considered as a 6 molar (6 M) solution of NaCl, has a density of 2 g mL\(^{-1}\). The concentration of dissolved oxygen (O\(_2\)) in sea water is 5.8 ppm. Then the concentration of dissolved oxygen (O\(_2\)) in sea water, in x \(\times\) 10\(^{-6}\) m. x = _______. (Nearest integer)

Given: Molar mass of NaCl is 58.5 g mol\(^{-1}\)
Molar mass of O\(_2\) is 32 g mol\(^{-1}\).


Question 22:

The amount of calcium oxide produced on heating 150 kg limestone (75% pure) is _______ kg. (Nearest integer)

Given: Molar mass (in g mol\(^{-1}\)) of Ca-40, O-16, C-12


Question 23:

A metal complex with a formula MC\(\ell_4\)3NH\(_3\) is involved in sp\(^3\)d\(^2\) hybridisation. It upon reaction with excess of AgNO\(_3\) solution gives ‘x’ moles of AgCl. Consider ‘x’ is equal to the number of lone pairs of electron present in central atom of BrF\(_5\). Then the number of geometrical isomers exhibited by the complex is ________


Question 24:

The molar conductance of an infinitely dilute solution of ammonium chloride was found to be 185 S cm\(^{-1}\) mol\(^{-1}\) and the ionic conductance of hydroxyl and chloride ions are 170 and 70 S cm\(^{-1}\) mol\(^{-1}\), respectively. If molar conductance of 0.02 M solution of ammonium hydroxide is 85.5 S cm\(^{-1}\) mol\(^{-1}\), its degree of dissociation is given by x \(\times\) 10\(^{-1}\). The value of x is ______. (Nearest integer)


Question 25:

x mg of Mg(OH)\(_2\) (molar mass = 58) is required to be dissolved in 1.0 L of water to produce a pH of 10.0 at 298 K. The value of x is ____ mg. (Nearest integer)

(Given: Mg(OH)\(_2\) is assumed to dissociate completely in H\(_2\)O)



JEE Main Questions

  • 1.

    In the following substitution reaction:


    • 2.
      Given below are two statements: Statement (I): The radius of isoelectronic species increases in the order. \[ {Mg}^{2+}<{Na}^+<{F}^-<{O}^{2-} \] Statement (II): The magnitude of electron gain enthalpy of halogens decreases in the order. \[ {Cl}>{F}>{Br}>{I} \] In light of the above statements, choose the most appropriate answer from the options given below:

        • Both Statement I and Statement II are correct.
        • Statement I is incorrect but Statement II is correct.
        • Statement I is correct but Statement II is incorrect.
        • Both Statement I and Statement II are incorrect.

      • 3.

        Given below are two statements: 
        Statement I: Experimentally determined oxygen-oxygen bond lengths in the \( O_2 \) are found to be the same and the bond length is greater than that of a \( O=O \) (double bond) but less than that of a single \( O-O \) bond. 
        Statement II: The strong lone pair-lone pair repulsion between oxygen atoms is solely responsible for the fact that the bond length in ozone is smaller than that of a double bond \( O=O \) but more than that of a single bond \( O-O \). 
        In light of the above statements, choose the correct answer from the options given below:

          • Statement I is true but Statement II is false
          • Statement I is false but Statement II is true
          • Both Statement I and Statement II are false
          • Both Statement I and Statement II are true

        • 4.

          The major product (A) formed in the following reaction sequence is


          • 5.
            The successive 5 ionisation energies of an element are 800, 2427, 3658, 25024 and 32824 kJ/mol, respectively. By using the above values, predict the group in which the above element is present:

              • Group 4
              • Group 14
              • Group 2
              • Group 13

            • 6.
              Match List - I with List - II: List - I: (A) \( {[MnBr}_4]^{2-} \)
              (B) \( {[FeF}_6]^{3-} \)
              (C) \( {[Co(C}_2{O}_4)_3]^{3-} \)
              (D) \( [Ni(CO)_4] \)
              List - II: (I) \( d^2sp^3 \) & diamagnetic
              (II) \( sp^2d^2 \) & paramagnetic
              (III) \( sp^3 \) & diamagnetic
              (IV) \( sp^3 \) & paramagnetic
              Choose the correct answer from the options given below:

                • \( {(A)-(III)}, {(B)-(II)}, {(C)-(I)}, {(D)-(IV)} \)
                • \( {(A)-(IV)}, {(B)-(I)}, {(C)-(II)}, {(D)-(III)} \)
                • \( {(A)-(I)}, {(B)-(II)}, {(C)-(III)}, {(D)-(IV)} \)
                • \( {(A)-(IV)}, {(B)-(I)}, {(C)-(III)}, {(D)-(II)} \)

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