JEE Main 2025 April 3 Shift 1 Chemistry Question Paper, Exam Analysis, and Answer Keys (Available)

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Shivam Yadav

Updated on - Nov 26, 2025

JEE Main 2025 April 3 Chemistry Question Paper is available for download. NTA conducted JEE Main 2025 Shift 1 B.Tech Exam on 3rd April 2025 from 9:00 AM to 12:00 PM and for JEE Main 2025 B.Tech Shift 2 appearing candidates from 3:00 PM to 6:00 PM. The JEE Main 2025 3rd April B.Tech Question Paper was Moderate to Tough.

Also Check: JEE Main 2025 Question Paper with Solution PDF Download

JEE Main 2025 April 3 Shift 1 Chemistry Question Paper with Solutions

JEE Main 2025 April 3 Shift 1 Chemistry Question Paper Pdf Download PDF View Solution

JEE Main 2025 Chemistry Questions with Solutions

Question 1:

Which of the following postulate of Bohr's model of hydrogen atom in not in agreement with quantum mechanical model of an atom ?

  • (1) An atom in a stationary state does not emit electromagnetic radiation as long as it stays in the same state
  • (2) An atom can take only certain distinct energies \( E_1 \), \( E_2 \), \( E_3 \), etc. These allowed states of constant energy are called the stationary states of atom
  • (3) When an electron makes a transition from a higher energy stationary state to a lower energy stationary state, then it emits a photon of light
  • (4) The electron in a H atom's stationary state moves in a circle around the nucleus

Question 2:

Given below are two statements:
Statement I : The N-N single bond is weaker and longer than that of P-P single bond
Statement II : Compounds of group 15 elements in +3 oxidation states readily undergo disproportionation reactions.
In the light of above statements, choose the correct answer from the options given below

  • (1) Statement I is true but Statement II is false
  • (2) Both Statement I and Statement II are false
  • (3) Statement I is false but Statement II is true
  • (4) Both Statement I and Statement II are true

Question 3:

Given below are two statements:


Statement I: A catalyst cannot alter the equilibrium constant (\( K_c \)) of the reaction, temperature remaining constant.


Statement II: A homogeneous catalyst can change the equilibrium composition of a system, temperature remaining constant.


In the light of the above statements, choose the correct answer from the options given below.

  • (1) Statement I is false but Statement II is true
  • (2) Both Statement I and Statement II are true
  • (3) Both Statement I and Statement II are false
  • (4) Statement I is true but Statement II is false

Question 4:

The metal ions that have the calculated spin only magnetic moment value of 4.9 B.M. are
A. \( Cr^{2+} \)
B. \( Fe^{2+} \)
C. \( Fe^{3+} \)
D. \( Co^{2+} \)
E. \( Mn^{2+} \)
Choose the correct answer from the options given below

  • (1) A, C and E only
  • (2) B and E only
  • (3) B and E only
  • (4) A, B and E only

Question 5:

In a reaction A + B → C, initial concentrations of A and B are related as \( [A]_0 = 8[B]_0 \). The half lives of A and B are 10 min and 40 min, respectively. If they start to disappear at the same time, both following first order kinetics, after how much time will the concentration of both the reactants be same?

  • (1) 60 min
  • (2) 80 min
  • (3) 20 min
  • (4) 40 min

Question 6:

Which of the following is the correct structure of L-fructose?

  • (1)
  • (2)
  • (3)
  • (4)

Question 7:

Identify the correct statements from the following

A. image

B. image

C. image

D. image

Choose the correct answer from the options given below

  • (1) C and D only
  • (2) B and C only
  • (3) A and B only
  • (4) A, B and C only

Question 8:

Among \( 10^{-10} \) g (each) of the following elements, which one will have the highest number of atoms?

Element : Pb, Po, Pr and Pt

  • (1) Po
  • (2) Pr
  • (3) Pb
  • (4) Pt

Question 9:

Which of the following statements are correct?
A. The process of the addition an electron to a neutral gaseous atom is always exothermic
B. The process of removing an electron from an isolated gaseous atom is always endothermic
C. The 1st ionization energy of the boron is less than that of the beryllium
D. The electronegativity of C is 2.5 in \( CH_4 \) and \( CCl_4 \)
E. Li is the most electropositive among elements of group 1
Choose the correct answer from the options given below

  • (1) B and C only
  • (2) A, C and D only
  • (3) B and D only
  • (4) B, C and E only

Question 10:

Which of the following properties will change when system containing solution 1 will become solution 2 ?


  • (1) Molar heat capacity
  • (2) Density
  • (3) Concentration
  • (4) Gibbs free energy

Question 11:

Number of molecules from below which cannot give iodoform reaction is:
Ethanol, Isopropyl alcohol, Bromoacetone, 2-Butanol, 2-Butanone, Butanal, 2-Pentanone, 3-Pentanone, Pentanal and 3-Pentanol

  • (1) 2
  • (2) 4
  • (3) 3
  • (4) 2

Question 12:

Identify [A], [B], and [C], respectively in the following reaction sequence :

  • (1)
  • (2)
  • (3)
  • (4)

Question 13:

In the following reactions, which one is NOT correct?

  • (1)
  • (2)
  • (3)
  • (4)

Question 14:

The correct order of the complexes
[5pt] \([Co(NH_3)_5(H_2O)]^{3+}\) (A),
[3pt] \([Co(NH_3)_6]^{3+}\) (B),
[3pt] \([Co(CN)_6]^{3-}\) (C),
[3pt] \([CoCl(NH_3)_5]^{2+}\) (D)
[5pt]
in terms of wavelength of light absorbed is:

  • (1) D \(>\) A \(>\) B \(>\) C
  • (2) C \(>\) B \(>\) D \(>\) A
  • (3) D \(>\) C \(>\) B \(>\) A
  • (4) C \(>\) B \(>\) A \(>\) D

Question 15:

In the following system, \( PCl_5(g) \rightleftharpoons PCl_3(g) + Cl_2(g) \) at equilibrium, upon addition of xenon gas at constant T and p, the concentration of

  • (1) \( PCl_5 \) will increase
  • (2) \( Cl_2 \) will decrease
  • (3) \( PCl_5 \), \( PCl_3 \) and \( Cl_2 \) remain constant
  • (4) \( PCl_3 \) will increase

Question 16:

2 moles each of ethylene glycol and glucose are dissolved in 500 g of water. The boiling point of the resulting solution is: (Given: Ebullioscopic constant of water = \( 0.52 \, K kg mol^{-1} \))

  • (1) 379.2 K
  • (2) 377.3 K
  • (3) 375.3 K
  • (4) 277.3 K

Question 17:

Which compound would give 3-methyl-6-oxoheptanal upon ozonolysis ?

  • (1)
  • (2)
  • (3)
  • (4)

Question 18:

Match the LIST-I with LIST-II

LIST-I                            LIST-II

A. \( PF_5 \)                 I. \( dsp^2 \)

B. \( SF_6 \)                 II. \( sp^3d \)
 
C. \( Ni(CO)_4 \)          III. \( sp^3d^2 \)

D. \( [PtCl_4]^{2-} \)   IV. \( sp^3 \)

Choose the correct answer from the options given below :

  • (1) A-II, B-III, C-IV, D-I
  • (2) A-IV, B-I, C-II, D-III
  • (3) A-I, B-II, C-III, D-IV
  • (4) A-III, B-I, C-IV, D-II

Question 19:

The least acidic compound, among the following is
image

  • (1) D
  • (2) A
  • (3) B
  • (4) C

Question 20:

Correct order of limiting molar conductivity for cations in water at 298 K is :

  • (1) \( H^+ > K^+ > Ca^{2+} > Mg^{2+} \)
  • (2) \( H^+ > Ca^{2+} > Mg^{2+} > K^+ \)
  • (3) \( Mg^{2+} > H^+ > Ca^{2+} > K^+ \)
  • (4) \( H^+ > Na^+ > Ca^{2+} > Mg^{2+} > K^+ \)

Question 21:

During estimation of Nitrogen by Dumas' method of compound X (0.42 g) :

image

mL of \( N_2 \) gas will be liberated at STP. (nearest integer)
(Given molar mass in g \(mol^{-1}\) : C : 12, H : 1, N : 14)


Question 22:

0.5 g of an organic compound on combustion gave 1.46 g of \( CO_2 \) and 0.9 g of \( H_2O \). The percentage of carbon in the compound is ______ (Nearest integer)
(Given : Molar mass (in g \(mol^{-1}\)) C : 12, H : 1, O : 16)


Question 23:

The number of optical isomers exhibited by the iron complex (A) obtained from the following reaction is ______ \( FeCl_3 + KOH + H_2C_2O_4 \rightarrow A \)


Question 24:

Given: \( \Delta H_f^0 [C(graphite)] = 710 \) kJ mol⁻¹ \( \Delta_c H^0 = 414 \) kJ mol⁻¹ \( \Delta_{H-H}^0 = 436 \) kJ mol⁻¹ \( \Delta_{C-H}^0 = 611 \) kJ mol⁻¹
The \(\Delta\) \(H_{C=C}^0\) for \(CH_2=CH_2\) is ______ kJ \(mol^{-1}\) (nearest integer value)


Question 25:

Consider the following reactions \( A + HCl + H_2SO_4 \rightarrow CrO_2Cl_2 + Side Products \)
Little amount \( CrO_2Cl_2(vapour) + NaOH \rightarrow B + NaCl + H_2O \) \( B + H^+ \rightarrow C + H_2O \)
The number of terminal 'O' present in the compound 'C' is ______



JEE Main 2025 April 3 Shift 1 Chemistry Exam Analysis

Aspect Details
Overall Difficulty The Chemistry section of the JEE Main 2025 April 3 Shift 1 exam was considered easy to moderate. Students found the questions straightforward, with a focus on fundamental concepts and NCERT-based topics.
Time Consumption The Chemistry section was time-efficient for most students. Many candidates were able to complete it in about 40 minutes, allowing ample time for revision.
Topic Distribution
  • Physical Chemistry: Featured 6-7 questions, including numerical problems focused on topics like Chemical Kinetics, Mole Concept, and Thermodynamics.
  • Organic Chemistry: Dominated with 8-10 questions, mainly covering General Organic Chemistry (GOC), Reaction Mechanisms, and Functional Groups.
  • Inorganic Chemistry: Featured questions from topics like Coordination Compounds, Periodic Table Trends, and Biomolecules.
Question Types The questions included a mixture of multiple-choice questions (MCQs) and numerical value-based questions, testing both conceptual understanding and application of chemical principles.
Student Feedback Students reported that the Chemistry section was balanced, with clear and NCERT-aligned questions. Organic Chemistry was the most prominent topic, and many students found the section well within their preparation range.

Also Check JEE Main 2025 April 2 Shift 1 Question Paper With Video Solutions

Get the JEE Main 2025 April 2 Shift 1 Question Paper with detailed video solutions. Compare answers with the official answer key and understand the difficulty level for upcoming shifts..

JEE Main Questions

  • 1.

    Given below are two statements: 
    Statement I: Experimentally determined oxygen-oxygen bond lengths in the \( O_2 \) are found to be the same and the bond length is greater than that of a \( O=O \) (double bond) but less than that of a single \( O-O \) bond. 
    Statement II: The strong lone pair-lone pair repulsion between oxygen atoms is solely responsible for the fact that the bond length in ozone is smaller than that of a double bond \( O=O \) but more than that of a single bond \( O-O \). 
    In light of the above statements, choose the correct answer from the options given below:

      • Statement I is true but Statement II is false
      • Statement I is false but Statement II is true
      • Both Statement I and Statement II are false
      • Both Statement I and Statement II are true

    • 2.
      The most stable carbocation from the following is:

        •  stable carbocation
        •  stable carbocation
        •  stable carbocation
        •  stable carbocation

      • 3.
        The correct increasing order of stability of the complexes based on \( \Delta \) value is:

          • \( {IV}<{III}<{II}<{I} \)
          • \( {I}<{II}<{IV}<{III} \)
          • \( {III}<{II}<{IV}<{I} \)
          • \( {II}<{III}<{I}<{IV} \)

        • 4.
          The molar conductivity of a weak electrolyte when plotted against the square root of its concentration, which of the following is expected to be observed?

            • A small decrease in molar conductivity is observed at infinite dilution.
            • A small increase in molar conductivity is observed at infinite dilution.
            • Molar conductivity increases sharply with increase in concentration.
            • Molar conductivity decreases sharply with increase in concentration.

          • 5.
            Find the compound \( A \) from the following reaction sequences: \[ A \xrightarrow{\text{aqua regia}} B \xrightarrow{(1) \, \text{KNO}_3, \, \text{NH}_4\text{OH}} \text{yellow ppt}. \]

              • \( \text{CoS} \)
              • \( \text{NiS} \)
              • \( \text{ZnS} \)
              • \( \text{MnS} \)

            • 6.
              The conditions and consequences that favour the \( t_{2g}^3 e_g^1 \) configuration in a metal complex are:

                • Weak field ligand, low spin complex
                • Strong field ligand, low spin complex
                • Strong field ligand, high spin complex
                • Weak field ligand, high spin complex

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