JEE Main 2025 April 2 Shift 1 Chemistry Question Paper, Exam Analysis, and Answer Keys (Available)

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Shivam Yadav

Updated on - Nov 26, 2025

JEE Main 2025 April 2 Chemistry Question Paper is available for download. NTA conducted JEE Main 2025 Shift 1 B.Tech Exam on 3rd April 2025 from 9:00 AM to 12:00 PM and for JEE Main 2025 B.Tech Shift 2 appearing candidates from 3:00 PM to 6:00 PM. The JEE Main 2025 2nd April B.Tech Question Paper was Moderate to Tough.

Also Check: JEE Main 2025 Question Paper with Solution PDF Download

JEE Main 2025 April 2 Shift 1 Chemistry Question Paper with Solutions

JEE Main 2025 April 2 Shift 1 Chemistry Question Paper Pdf Download PDF View Solution


Question 1:

Designate whether each of the following compounds is aromatic or not aromatic.


 


Question 2:

An optically active alkyl halide C\(_4\)H\(_9\)Br [A] reacts with hot KOH dissolved in ethanol and forms alkene [B] as major product which reacts with bromine to give dibromide [C]. The compound [C] is converted into a gas [D] upon reacting with alcoholic NaNH\(_2\). During hydration 18 gram of water is added to 1 mole of gas [D] on warming with mercuric sulphate and dilute acid at 333 K to form compound [E]. The IUPAC name of compound [E] is :

(1) But-2-yne
(2) Butan-2-ol
(3) Butan-2-one
(4) Butan-1-al


Question 3:

The property/properties that show irregularity in the first four elements of group-17 are:

  • (A) Covalent radius
  • (B) Electron affinity
  • (C) Ionic radius
  • (D) First ionization energy
    Choose the correct answer from the options given below:
  • (1) B and D only
  • (2) A and C only
  • (3) B only
  • (4) A, B, C and D

Question 4:

Which of the following graph correctly represents the plots of \(K_H\) at 1 bar gases in water versus temperature?

  • (2) 
    (3)  
  • (4) 

Question 5:

According to Bohr's model of hydrogen atom, which of the following statement is incorrect?

  • (1) Radius of 3rd orbit is nine times larger than that of 1st orbit. 
  • (2) Radius of 8th orbit is four times larger than that of 4th orbit. 
  • (3) Radius of 6th orbit is three times larger than that of 4th orbit. 
  • (4) Radius of 4th orbit is four times larger than that of 2nd orbit.

Question 6:

Two vessels A and B are connected via stopcock. Vessel A is filled with a gas at a certain pressure. The entire assembly is immersed in water and allowed to come to thermal equilibrium with water. After opening the stopcock the gas from vessel A expands into vessel B and no change in temperature is observed in the thermometer. Which of the following statement is true?

  • (1) \( dw = 0 \)
    (2) \( dq = 0 \)
    (3) \( du = 0 \)
    (4) The pressure in the vessel B before opening the stopcock is zero

Question 7:

A solution is made by mixing one mole of volatile liquid A with 3 moles of volatile liquid B. The vapor pressure of pure A is 200 mm Hg and that of the solution is 500 mm Hg. The vapor pressure of pure B and the least volatile component of the solution, respectively, are:

  • (1) 1400 mm Hg, A
    (2) 1400 mm Hg, B
    (3) 600 mm Hg, A
  • (4) 600 mm Hg, B

Question 8:

Consider the above reaction, what mass of CaCl₂ will be formed if 250 ml of 0.76 M HCl reacts with 1000 g of CaCO₃?

  • (1) 3.908 g
  • (2) 2.636 g
    (3) 10.545 g
  • (4) 5.272 g

Question 9:

If equal volumes of AB and XY (both are salts) aqueous solutions are mixed, which of the following combination will give precipitate of AY, at 300 K?

  • (1) \( K \) (300 K) for \( AB \) = \( 5.2 \times 10^3 \)
    (2) \( K \) (300 K) for \( AB \) = \( 1.0 \times 10^3 \)
    (3) \( K \) for \( 10^{-10} \, M \, AB \), \( 5 \times 10^{-10} \, M \, XY \)
    (4) \( K \) for \( 15 \times 10^{-10} \, M \, XY \)

Question 10:

Among SO₃, NF₃, NH₃, XeF₂, CIF, and SF₆, the hybridization of the molecule with non-zero dipole moment and one or more lone-pairs of electrons on the central atom is:

  • (1) \( sp^3 \)
    (2) \( sp^2 \)
    (3) \( sp^3d^2 \)
    (4) \( sp^3d \)

Question 11:

Given below are two statements:

Statement I: Vanillin will react with NaOH and also with Tollen’s reagent.




Statement II: Vanillin will undergo self-aldol condensation very easily.

 


In the light of the above statements, choose the most appropriate answer from the options given below:


Question 12:

Identify the correct statement among the following:

  • (1) All naturally occurring amino acids except glycine contain one chiral centre.
    (2) All naturally occurring amino acids are optically active.
    (3) Glutamic acid is the only amino acid that contains a –COOH group at the side chain.
    (4) Amino acid, cysteine easily undergoes dimerization due to the presence of free SH group.

Question 13:

The correct order of basic nature on aqueous solution for the bases \( NH_3 \), \( NH_2 \), \( CH_3 NH_2 \), \( CH_3 CH_2 NH_2 \), \( (CH_3 CH_2)_2 NH \) is:

  • (1) \( NH_3 > NH_2 > CH_3 NH_2 > CH_3 CH_2 NH_2 > (CH_3 CH_2)_2 NH \)
    (2) \( NH_2 > NH_3 > CH_3 NH_2 > CH_3 CH_2 NH_2 > (CH_3 CH_2)_2 NH \)
    (3) \( NH_3 > CH_3 NH_2 > NH_2 > CH_3 CH_2 NH_2 > (CH_3 CH_2)_2 NH \)
    (4) \( NH_3 > CH_3 CH_2 NH_2 > NH_2 > CH_3 NH_2 > (CH_3 CH_2)_2 NH \)

Question 14:

Given below are two statements:

Statement I: The metallic radius of Al is less than that of Ga.


Statement II: The ionic radius of Al\(^{3+}\) is less than that of Ga\(^{3+}\).


In the light of the above statements, choose the most appropriate answer from the options given below:


Question 15:

Given below are two statements:

Statement I: High spin complexes have high values of \( \Delta_o \).


Statement II: Low spin complexes are formed when \( \Delta_o \) is high.


In the light of the above statements, choose the most appropriate answer from the options given below:


Question 16:

Choose the correct sets with respective observations:

(1) \( CuSO_4 \) (acidified with acetic acid) + \( K_2Fe(CN)_6 \) (neutralized with NaOH) → Blue precipitate


(2) \( 2CuSO_4 \) + \( K_2Fe(CN)_6 \) → Blue precipitate


(3) \( 4FeCl_3 \) + \( 3K_4Fe(CN)_6 \) → \( \frac{1}{2}K_4Fe(CN)_6 \)


(4) \( 37Cl_2 \) + \( 2KFe(CN)_6 \) → 6KC1


In the light of the above options, choose the correct set:


Question 17:

On complete combustion 1.0 g of an organic compound (X) gave 1.46 g of CO₂ and 0.567 g of H₂O. The empirical formula mass of compound (X) is:

(Given molar mass in g mol\(^{-1}\): C: 12, H: 1, O: 16)

  • (1) 30
  • (2) 45
  • (3) 60
  • (4) 15

Question 18:

Consider the following compound (X):

 

The most stable and least stable carbon radicals, respectively, produced by homolytic cleavage of corresponding C - H bond are:

  • (1) I, IV
  • (2) III, II
  • (3) II, IV
  • (4) I, III

Question 19:

Consider the following molecules:

 

 

 





The order of rate of hydrolysis is:

  • (1) \( r > q > p > s \)
    (2) \( q > p > r > s \)
    (3) \( p > r > q > s \)
    (4) \( p > q > r > s \)

Question 20:

A molecule with the formula \( A X_2 Y_2 \) has all it's elements from p-block. Element A is rarest, monotomic, non-radioactive from its group and has the lowest ionization energy value among X and Y. Elements X and Y have first and second highest electronegativity values respectively among all the known elements. The shape of the molecule is:

  • (1) Square pyramidal
    (2) Octahedral
    (3) Planar
    (4) Tetrahedral

Question 21:

A transition metal (M) among Mn, Cr, Co, and Fe has the highest standard electrode potential \( M^{n}/M^{n+1} \). It forms a metal complex of the type \([M CN]^{n+}\). The number of electrons present in the \( e \)-orbital of the complex is …….


Question 22:

Consider the following electrochemical cell at standard condition.
\[ Au(s) | QH_2 | QH_X(0.01 M) \, | Ag(1M) | Ag(s) \, E_{cell} = +0.4V \]
The couple QH/Q represents quinhydrone electrode, the half cell reaction is given below: \[ QH_2 \rightarrow Q + 2e^- + 2H^+ \, E^\circ_{QH/Q} = +0.7V \]


 

  • (1) 6 (2) 5 (3) 4 (4) 3

Question 23:

0.1 mol of the following given antiviral compound (P) will weigh .........x \( 10^{-1} \) g.



 


Question 24:

Consider the following equilibrium,
\[ CO(g) + H_2(g) \rightleftharpoons CH_3OH(g) \]
0.1 mol of CO along with a catalyst is present in a 2 dm\(^3\) flask maintained at 500 K. Hydrogen is introduced into the flask until the pressure is 5 bar and 0.04 mol of CH\(_3\)OH is formed. The \( K_p \) is ...... x \( 10^7 \) (nearest integer).


Given: \( R = 0.08 \, dm^3 \, bar \, K^{-1} \, mol^{-1} \)


Assume only methanol is formed as the product and the system follows ideal gas behavior.


Question 25:

For the reaction \( A \rightarrow \) products,


 



The reaction was started with 2.5 mol L\(^{-1}\) of A.



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