NCERT Solutions For Class 12 Chemistry Chapter 9: Coordination Compounds

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Jasmine Grover

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NCERT Solutions for Class 12 Chemistry Chapter 9 Coordination Compounds discusses the composition of coordination compound surrounded by a particular number of oppositely charged ions or molecules that are neutrally charged. Some of the important topics in this chapter include:

  1. Werner’s Theory of Coordination Compounds
  2. Nomenclature of Coordination Compounds
  3. Isomerism in Coordination Compounds
  4. Bonding in Metal Carbonyls
  5. Organometallic Compounds
  6. Ligands
  7. Cis Trans Isomerism

Expected no.of questions: 1 to 5 questions of total 7 marks

Download PDF: NCERT Solutions for Class 12 Chemistry Chapter 9 pdf


NCERT Solutions for Class 12 Chemistry Chapter 9

The NCERT Solutions for class 12 Chemistry chapter 9 are as given below.

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Class 12 Chemistry Chapter 9 Coordination Compounds – Important Topics

Coordination compounds are those which consists of a central metal atom which is bonded to oppositely charged ions. These compounds do not dissociate into their constituent particles even when they are dissolved.

  • Double salts are formed when two salts in a stoichiometric ratio crystallize together from their saturated solution. Eg: Mohr’s Salt
  • Ligands are atoms or groups that are directly attached to central atoms. A ligand is a lewis base.

Isomers are two or more compounds with the same chemical formula but different atomic arrangements. It is of two types.

A. Stereomerism

  • Geometrical Isomerism
  • Optical Isomerism

​B. Structural Isomerism

  • Linkage Isomerism
  • Coordinations Isomerism
  • Ionisation Isomerism
  • Solvate Isomerism

Metal carbonyls are homoleptic complexes in which carbon monoxide (CO) serves as the ligand.

Lewis Base: A Lewis base is a species that has a lone pair of electrons and can donate a pair of electrons to form a covalent bond. 

Lewis Acid: The chemical species with empty orbitals that can accept a pair of electrons from the Lewis bases are called Lewis acids.


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CBSE CLASS XII Related Questions

1.
Define the term solution. How many types of solutions are formed? Write briefly about each type with an example.

      2.

      Give the IUPAC names of the following compounds:

      (i)CH3CH(Cl)CH(Br)CH3

      (ii)CHF2CBrClF

      (iii)ClCH2C≡CCH2Br

      (iv)(CCl3)3CCl

      (v)CH3C(p-ClC6H4)2CH(Br)CH3

      (vi)(CH3)3CCH=CClC6H4I-p

          3.
          A solution of Ni(NO3)2 is electrolysed between platinum electrodes using a current of 5 amperes for 20 minutes. What mass of Ni is deposited at the cathode?

              4.

              Draw the structures of optical isomers of: 
              (i) \([Cr(C_2O_4)_3]^{3–}\)
              (ii) \([PtCl_2(en)_2]^{2+}\)
              (iii) \([Cr(NH_3)2Cl_2(en)]^{+}\)

                  5.
                  Write the Nernst equation and emf of the following cells at 298 K : 
                  (i) Mg(s) | Mg2+ (0.001M) || Cu2+(0.0001 M) | Cu(s) 
                  (ii) Fe(s) | Fe2+ (0.001M) || H+ (1M)|H2(g)(1bar) | Pt(s) 
                  (iii) Sn(s) | Sn2+(0.050 M) || H+ (0.020 M) | H2(g) (1 bar) | Pt(s) 
                  (iv) Pt(s) | Br2(l) | Br-  (0.010 M) || H+ (0.030 M) | H2(g) (1 bar) | Pt(s).

                      6.
                      Using the standard electrode potentials given in Table 3.1, predict if the reaction between the following is feasible: 
                      (i) Fe3+ (aq) and I- (aq) 
                      (ii) Ag+ (aq) and Cu(s) 
                      (iii) Fe3+(aq) and Br-(aq) 
                      (iv) Ag(s) and Fe3+(aq) 
                      (v) Br2 (aq) and Fe2+(aq).

                          CBSE CLASS XII Previous Year Papers

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