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Cobalt is a chemical component that has a place in the group IX of the periodic table, which can be utilized particularly for heat-resistant and magnetic combinations. It is like iron and nickel in its actual properties. Cobalt is found in plants and creatures, air, water, soil, rocks. It might likewise go into one more climate through wind-blown dust or by water washing down cobalt containing soil and rock.
The symbol of Cobalt is Co. This metal was found (c.1735) by a Swedish scientific expert named Georg Brandt, however the cobalt compounds had been utilized for quite a long time to give a blue tone to ceramics and glazes.
The oxidation number of cobalt in [Co(NH3)6]Cl2Br is given as +6, 0, +3, +2. Cobalt oxidation states are +2 and +3.
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Keyterms: Cobalt, Nickel, Periodic table, Metal, Oxidation state, Soil, Rock, Air, Water
About Cobalt
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Cobalt metal has been identified in the Persian neckband dots and Egyptian statuettes of the third thousand years BCE, in glass, which is found in the Pompeii ruins, and in China as ahead of schedule as the Tang tradition (618–907 CE) and from that point forward, in the blue porcelain of the Ming line (from 1368–1644). The term kobold was first applied (in the sixteenth century) to the minerals thought to contain copper, yet in the end, it was viewed as harmful arsenic-bearing cobalt metals. It was observed that the blue shade of those metals was a direct result of the presence of cobalt.
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Uses Of Cobalt
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- Cobalt is utilized in many alloys and superalloys to make parts in airplane motors, gas turbines, fast prepares, erosion safe combinations, solidified carbides.
- It is utilized in magnets and attractive recording media. .
- It is additionally utilized as impetus for the petrol and synthetic businesses.
- It is used as drying specialists for paints and inks.
- It is significantly utilized by craftsmen and by creating labourers in porcelain, stained-glass stoneware, finish gem dealer, and tiles.
- The radioactive isotopes, cobalt-60, is utilized in clinical therapy and furthermore to irradiate food. It is utilized to safeguard the food and secure the shopper.
Properties Of Cobalt
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- It is a hard ferromagnetic, silver-white, radiant, weak element.
- It is steady in air and doesn’t respond with water.
- Like other metals, it can likewise be polarized.
- With weaker acids, it responds slowly.
- The metal melts at 1495 °C and boils at 2927 °C
Characteristics of Cobalt
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- Cobalt is a ferromagnetic metal having a particular gravity of 8.9.
- The Curie temperature is 1,115 °C, and the magnetic moment is 1.6–1.7 Bohr magnetons per atom.
- Cobalt contains a relative penetrability 66% that of iron. Metallic cobalt is found as two crystallographic structures: fcc and hcp.
- The ideal change temperature between the fcc and hcp structures is given as 450 °C, yet practically speaking, the energy contrast between them is entirely little, to the point that the arbitrary intergrowth of the two is exceptionally normal.
Occurrence of Cobalt
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The stable type of the cobalt metal can be created in supernovae through the r-process. It contains a level of 0.0029 of the covering of Earth. Free cobalt (which is the local metal) isn’t seen as on Earth because of the chlorine in the sea and oxygen in the environment.
Both of these are plentiful enough in the upper layers of the covering of Earth to keep local metal cobalt from producing. Pure cobalt metal in the local metal created on Earth is not known, besides as of late conveyed in meteoric iron. Additionally, this component contains a medium abundance, though the normal mixtures of cobalt are various, and the modest quantities are found in many soils, rocks, creatures, and plants.
Production of Cobalt
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The essential minerals of cobalt metal are erythrite, cobaltite, skutterudite, and glaucodot, however most cobalt can be acquired by decreasing the cobalt results of copper and nickel mining and refining.
Since cobalt is part shaped as a by-product, the inventory of this metal depends, generally, on the economic reasonability of the nickel and copper mining activities in the market.
Application Of Cobalt
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There are numerous applications concerning cobalt metal:
Alloys
Cobalt-based superalloys are very useful. The security of temperature of these combinations makes them reasonable for turbine edges for airplane fly motors and gas turbines, albeit the nickel-based single-precious stone composites will outperform them in execution. Likewise, the cobalt-based compounds are erosion – and wear-safe by making them, for example, valuable for making muscular inserts that don’t wear out over the long haul.
Batteries
Lithium cobalt oxide (LiCoO2) can be utilized generally in lithium-particle battery cathodes. This material is blended in with cobalt oxide layers with lithium intercalated. During the release, the lithium discharges lithium particles. Nickel metal hydride (NiMH) and Nickel-cadmium (NiCd) batteries likewise incorporate cobalt to further develop the nickel oxidation present in the battery.
Health Impacts of Cobalt
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Cobalt is viewed as a fundamental component for minute measures of life. The LD50, an incentive for the solvent cobalt salts has been assessed to be in a scope of 150 – 500 mg/kg. In the US, the OSHA – Occupational Safety and Health Administration has assigned a passable openness limit (PEL) of cobalt in the working environment as a TWA – Time-Weighted Average of 0.1 mg/m3. Likewise, the NIOSH – National Institute for Occupational Safety and Health has drawn a suggested openness line (REL) to 0.05 mg/m3, a period weighted normal.
Things to Remember
- Cobalt is a chemical component placed in the group IX of the periodic table,
- Cobalt is a hard ferromagnetic, silver-white, radiant, weak element.
- Cobalt has a melting point of 2,723 degrees Fahrenheit (1,495 degrees Celsius).
- The Boiling point of cobalt is 5,301 F (2,927o C).
- The most common isotope of cobalt is Co-59 (100 percent natural abundance).
- Erythrite, cobaltite, skutterudite, and glaucodot are used to acquire cobalt.
- Cobalt is utilized in many alloys and superalloys and it is also used as drying specialists for paints and inks.
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Sample Questions
Ques: In Mendeleev’s periodic table, the elements were arranged in the increasing order of their atomic masses. However, cobalt with an atomic mass of 58.93 amu was placed before nickel having an atomic mass of 58.71 amu. Give reason for the same. (2 marks)
Ans: In Mendeleev’s periodic table, the reasons for placing cobalt (Co) before nickel (Ni) though its atomic mass is higher than that of nickel, are:
(i) Cobalt was placed in the group of rhodium (Rh) and iridium (Ir) because it exhibits the properties similar to them.
(ii) Similarly Nickel was placed with elements like palladium (Pd) and platinum (Pt) having properties similar to it.
Ques: Give the use of cobalt as catalysts. (2 marks)
Ans: Numerous cobalt compounds are used as oxidation impetuses. Cobalt acetic acid derivation can be utilized to change over the xylene into terephthalic corrosive, which is the forerunner of the mass polymer polyethylene terephthalate. Furthermore, the average impetuses are the cobalt carboxylates (likewise called cobalt cleansers). They can likewise be utilized in stains, paints, and inks as "drying specialists" through the oxidation of drying oils. The equivalent carboxylates can be utilized to work on the attachment among elastic and steel in the steel-belted spiral tires. Likewise, these are utilized as gas pedals in polyester tar frameworks.
Ques: Explain how cobalt is used in electronics? (2 marks)
Ans: Cobalt is a crucial element in modern electronics. The largest use of cobalt is as an additive in various types of NiCad and NiMH rechargeable batteries and as lithium cobalt oxide in the cathodes of lithium-ion batteries. It is also used in complex integrated circuits, which are used in computers, cellphones, and other electronic goods. It also reduces the physical movement of copper atoms that are present in the microscopic interconnecting paths (or electromigration) because of the passage of electrical currents.
Ques: What is cobalt? What are its uses? (2 marks)
Ans: Cobalt is silver-white magnetic metal, represented with the symbol ‘Co’ and has an atomic number of 27 . It is utilized in lithium-ion batteries, and in the manufacture of magnetic, wear-resistant and high-strength alloys.
Ques: Which metal can become a substitute for cobalt in batteries? (2 marks)
Ans: Nothing can replace the cobalt metal in a battery. If we tried, we would have to change the anode, which would make it a new battery type. We could also replace it with carbon and use zinc as a cathode with an electrolyte between them. That becomes an inexpensive battery to produce. Similar to any battery, it would have advantages and disadvantages. It would produce more current and is reliable.
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