NCERT Solutions For Class 12 Chemistry Chapter 3: Electrochemistry

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Jasmine Grover

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NCERT Solutions for class 12 Chemistry Chapter 3 Electrochemistry are provided in this article. It consists of all important formulas, chemical equations, important laws and numericals. Important topics covered in Class 12 Chemistry Chapter 3 Electrochemistry are:

  1. Electrochemical Cell
  2. Nernst Equation
  3. Electrolytic Cells and Electrolysis
  4. Fuel Cells
  5. Electrolytic & Galvanic Cells
  6. Anode and Cathode
  7. Batteries

Expected No.of Questions: 2 to 4 questions of 9 marks

Download PDF: NCERT Solutions for Class 12 Chemistry Chapter 3 Electrochemistry PDF


NCERT Solutions for Class 12 Chemistry Chapter 3

NCERT Solutions PDF for Class 12 Chemistry Chapter 3 Electrochemistry is given below.

NCERT Solutions

NCERT Solutions

NCERT Solutions

NCERT Solutions

NCERT Solutions

NCERT Solutions

NCERT Solutions

NCERT Solutions

NCERT Solutions

NCERT Solutions

NCERT Solutions

NCERT Solutions

NCERT Solutions

NCERT Solutions

NCERT Solutions

NCERT Solutions

NCERT Solutions

NCERT Solutions

NCERT Solutions

NCERT Solutions

NCERT Solutions

NCERT Solutions

NCERT Solutions


Class 12 Chemistry Chapter 3: Electrochemistry – Important Topics

Important topics of Class 12 Chemistry Chapter 3 Electrochemistry includes the following.

Electrochemistry deals with the study of electricity in chemistry involving electrodes, electrolysis, solutions and solvents. This mechanism is commonly seen in Electrochemical cells. There are two common types of electrochemical cells.

Galvanic Cell: In this, chemical energy is converted to electrical energy. It is also known as voltaic cell. Here, the anode is negatively charged and cathode is positively charged.

Electrolytic Cell: In this, electrical energy is converted to chemical energy. Here, the cathode is negatively charged and anode is positively charged.

Standard Electrode Potential is the standard EMF of the cell. The potential difference between the electrode and electrolyte is known as the potential of electrode and at unit concentration.

E0Cell = E0red, Cathode – E0red, Anode

Nernst equation is establishes the relation between the cell potential of an electrochemical cell, the standard cell potential, temperature, and the reaction quotient. 

\(E_{cell} = E^0 _{cell} - \frac{RT}{nF}ln Q\)

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CBSE CLASS XII Related Questions

  • 1.
    A solution is prepared by dissolving 0.025 g of potassium sulphate in 2 L of water at 27$^\circ$C. Assuming potassium sulphate is completely dissociated, determine its osmotic pressure. Given: \[ R=0.082 \, L\,atm\,K^{-1}mol^{-1} \] \[ \text{Molar mass of }K_2SO_4=174\,g\,mol^{-1} \] (ii) What type of azeotrope will be formed by a solution of acetone and chloroform? Give reason.


      • 2.
        Calculate the freezing point of a solution when 10.5 g of MgBr$_2$ was dissolved in 250 g of water, assuming MgBr$_2$ undergoes complete dissociation. Given: \[ \text{Molar mass of MgBr}_2 = 184 \, g\,mol^{-1} \] \[ K_f \text{ for water} = 1.86 \, K\,kg\,mol^{-1} \] (ii) Write two differences between ideal and non-ideal solutions.


          • 3.
            How much charge in faraday is required for the reduction of 1 mol of Ag$^+$ to Ag?


              • 4.
                The following reactions occur at the anode during the electrolysis of aqueous sodium chloride solution: \[ Cl^-_{(aq)} \rightarrow \frac{1}{2}Cl_2(g)+e^- \qquad E^\circ_{\text{cell}}=1.36\,V \] \[ 2H_2O(l) \rightarrow O_2(g)+4H^+(aq)+4e^- \qquad E^\circ_{\text{cell}}=1.23\,V \] Which reaction is feasible at the anode and why?


                  • 5.
                    Answer the following: (I) Which isomer of C$_4$H$_9$Br is most reactive towards S$_N$1 reaction? (II) Predict the alkene that would be formed by dehydrohalogenation of 1-Bromo-1-methylcyclohexane. (III) Although chlorine shows strong $-I$ effect, yet it is ortho/para-directing in electrophilic aromatic substitution reactions. Why? (ii) Write the major product in the following reactions: (I)
                    (II)


                      • 6.
                        (I) Why do transition metals show variable oxidation states? (II) Out of Mn$^{2+}$ and Ti$^{2+}$ which will be more paramagnetic and why? Atomic No.: Ti = 22, Mn = 25 (III) Which ion is the strongest oxidising agent in the options given below: \[ Cr^{3+},\ V^{3+},\ Mn^{3+} \] Atomic No.: Cr = 24, V = 23, Mn = 25 (ii) Complete and balance the following equations: (I) \[ 2MnO_2+4KOH+O_2\rightarrow ? \] (II) \[ 5C_2O_4^{2-}+2MnO_4^-+16H^+\rightarrow ? \]

                          CBSE CLASS XII Previous Year Papers

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