NCERT Solution for class 12 Chemistry chapter 10: Haloalkanes and Haloarenes

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NCERT Solutions for Class 12 Chemistry chapter 10 Haloalkanes and Haloarenes deals with the study of important preparation methods, physical and chemical properties and the applications of the organohalogen compounds. Some of the important topics in the Haloalkanes and Haloarenes chapter include:

  1. Classification of Haloalkanes and Haloarenes
  2. Nomenclature of Haloalkanes and Haloarenes
  3. Physical Properties of Haloalkanes and Haloarenes
  4. Chemical Reactions of Haloalkanes and Haloarenes
  5. SN2 Reaction Mechanism
  6. Enantiomers
  7. Finkelstein Reaction
  8. Wurtz Reaction

Expected no. of questions: 2 to 3 questions of total 6 marks

Download PDF: NCERT Solutions for Class 12 Chemistry Chapter 10 pdf


NCERT Solutions for Class 12 Chemistry Chapter 10

NCERT Solutions for class 12 Chemistry chapter 10 are as given below. 

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Class 12 Chemistry Chapter 10 Haloalkanes & Haloarenes – Important Topics

Haloalkanes and Haloarenes are those hydrocarbons where one of the hydrogen-bonded to the central carbon atom is replaced by a halogen. Some examples of haloalkenes and haloarenes are chloramphenicol, chloroquine, Chlorofluorocarbon, etc.

Haloalkanes

  • Haloalkanes are made up of aliphatic alkanes.
  • The halogen atom is attached to the sp3 hybridized carbon atom of alkyl group.
  • Haloalkanes are saturated organic compounds and are odourless.
  • Haloalkanes precipitate in SN2 substitution reactions.
  • Example: CH3Cl (Methyl Chloride) and CH3CH2Br (Ethyl Bromide)

Haloarenes

  • Haloarenes consists of hydrocarbons with aromatic ring where one or more hydrogren is replaced by halogens.
  • The halogen atom is attached in the sp3 hybridized carbon atom of the alkyl group.
  • Haloarenes do not precipitate in SNsubstitution reactions.
  • Haloarenes have a sweet odour.
  • Example: Chlorobenzene, Bromobenzene.

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CBSE CLASS XII Related Questions

  • 1.
    Which of the reactions is used in the conversion of a ketone into hydrocarbon?

      • Reimer-Tiemann reaction
      • Wolff-Kishner reduction
      • Aldol condensation
      • Stephen reaction

    • 2.
      Half-life (\( t_{1/2} \)) of a first order reaction is 1386 s. The value of rate constant is:

        • \(0.5 \times 10^{-4} \, \text{s}^{-1}\)
        • \(5.0 \times 10^{-4} \, \text{s}^{-1}\)
        • \(0.5 \times 10^{-5} \, \text{s}^{-1}\)
        • \(0.5 \times 10^{-3} \, \text{s}^{-1}\)

      • 3.
        Which of the following reagents are used to prepare primary amines by Hofmann bromamide degradation reaction?

          • (i), (ii) and (iv)
          • (i) and (iii)
          • (i), (ii) and (iii)
          • (i), (iii) and (iv)

        • 4.
          Calculate emf of the following cell at 298 K: \[ \text{Cr(s)} \, | \, \text{Cr}^{3+} (aq) \, (0.1\, M) \; || \; \text{Fe}^{2+} (aq) \, (0.01\, M) \, | \, \text{Fe(s)} \] Given: \[ E^\circ_{\text{Cr}^{3+}/\text{Cr}} = -0.74 \, V, \quad E^\circ_{\text{Fe}^{2+}/\text{Fe}} = -0.44 \, V, \quad \log 10 = 1 \]


            • 5.
              The rate for the following reaction is given by: \[ A + B \rightarrow C, \quad \text{Rate} = k[A][B]^2 \] How is the rate affected if we double the concentration of B?


                • 6.
                  Which of the following is most basic?

                    • \( Mn_2O_7 \)
                    • \( MnO_2 \)
                    • \( MnO \)
                    • \( Mn_2O_3 \)
                  CBSE CLASS XII Previous Year Papers

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