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Classification of Elements and Periodicity in Properties deals with the concept of elements and their periodic classification in the modern periodic table as per the periodic law. The modern periodic table divides the elements into seven horizontal rows (periods) and eighteen vertical columns according to the sequence of their atomic numbers (groups). Atomic number increases in a pattern in a group but is consecutive in a period. The valence shell electrical arrangement and chemical characteristics of elements belonging to the same group are comparable. However, the valencies of the elements belonging to the same period are different because of the progressively increasing number of electrons from left to right.
Based on the electrical structures of all the elements, the periodic table can distinguish between four different sorts of elements. These are elements of the s-block, p-block, d-block, and f-block. Atomic sizes, ionization enthalpies, electron gain enthalpies, electronegativity, and valence electrons all exhibit periodic trends. The two ends of a period are where chemical reactivity is strongest, and the middle is where it is lowest. Due to the easiness of electron loss, periods on the left extreme are more reactive (or low ionization enthalpy).
Read More: Periodic Classification of Elements Important Questions
Here are some important MCQs on Classification of Elements and Periodicity in Properties for the students to help them test their knowledge on the given topic.
Ques 1. Examining periodic trends in the ________ is done using the periodic classification of elements.
- physical properties of elements
- recurring patterns in the chemical characteristics of components
- None of the above
- both (a) and (b)
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Ans. (D) Both (A) and (B)
Explanation: The electronic arrangement of atoms, which is used to study the physical and chemical properties of the elements, has a logical effect on the periodic classification of elements.
Ques 2. The ionization enthalpies of the elements decline from top to bottom in a group of the periodic table due to ________.
- Increased densities
- a decline in the reactivities of chemicals
- the expansion of the atomic size
- Reduced electronegativities are
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Ans. (C) the expansion of the atomic size
Explanation: The atomic size increases down the periodic table. Due to a rise in atomic size, a set of elements in the periodic table have ionization enthalpies that drop from top to bottom.
Ques 3. An element's electrical configuration is 1s2, 2s2, 2p6, 3s23p3. What is the atomic number of the element in the periodic table that is immediately below the one above?
- 30
- 35
- 33
- 48
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Ans. (B) 33
Explanation: The sum of all the electrons in the given electronic configuration will determine the atomic number. The element that is present just below the given element will have an outermost electronic configuration as 4s24p3, hence, its full electronic configuration will be 1s2,2s22p6,3s23p6,4s2, 3d10,4p2. Thus, its atomic number is 33.
Ques 4. Despite being in separate groups, lithium and magnesium have remarkably similar chemical makeup. It does so for several reasons, including the following:
- both can be found together in nature
- both have almost the same size
- both have similar electronic configurations
- and the ratio of their charge to size (i.e. charge density) is almost the same.
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Ans. (D) and the ratio of their charge to size (i.e. charge density) is almost the same.
Explanation: Their charge density, or the ratio of charge to size, is very similar. Even though they are grouped differently due to a diagonal relationship, lithium and magnesium have remarkably comparable chemical properties.
Read More: Ionization Energy Formula
Ques 5. What electronic arrangement of an atom has the lowest ionization enthalpy among the following?
- 1s2 2s2 2p3
- 1s2 2s2 2p63s1
- 1s2 2s2 2p6
- 1s2 2s2 2p5
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Ans. (B) 1s22s22p63s1
Explanation: The amount of energy needed to remove one electron from an isolated gaseous atom's outermost orbit is known as the ionization enthalpy. The ionization enthalpy is lowest for the electronic structure 1s22s22p63s1.
Ques 6. The atomic radii of the elements O, S, Se, and As are rising in size in the following order:
- As < S < O < Se
- Se < S < As < O
- O < S < As < Se
- O < S < Se < As
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Ans. (D) O < S < Se < As
Explanation: Atomic radii increase as you move down in a group as new shells are added one at a time, which is why O<S<Se. Additionally, As is in group 15 and has one fewer electron in its p orbital than group 16 elements, giving it a bigger atomic radius. Thus, O<S<Se<As.
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Ques 7. An element with the atomic number 15 has the following group number, valence electron count, and valency values, in that order:
- 16, 5 and 2
- 15, 5 and 3
- 16, 6 and 3
- 15, 6, and 2
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Ans. (B) 15, 5, and 3
Explanation: Atomic number 15 (Z) belongs to P, this can be written as [Ne] 3s23p3
Phosphorus is in group 15 of elements. In the ground state, the valence electron count for phosphorus is 5 and the valency is 3, from 3s23p3.
Ques 8. The period in the current periodic table denotes the value of the following quantities:
- Atomic Number
- Atomic Mass
- Principal Quantum Number
- Azimuthal Quantum Number
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Ans. (C) Principal Quantum Number
Explanation: The chemical elements are arranged in a periodic table according to their atomic number (the number of protons in the nucleus), electron configurations, and characteristic chemical properties. A period in the Modern Periodic Table is indicated by the value of the primary quantum number (n) for the outermost shell or the valence shell.
Ques 9. The cation's ionic radius is always __________
- a smaller radius than the radius of its atom
- the atomic radius plus
- equal to the atomic radius
- Impossible to anticipate
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Ans. (A) a smaller radius than the radius of its atom
Explanation: The cation's ionic radius is always less than its atomic radius. The loss of electrons produces cations. Ionic radius decreases as a result of the rise in effective nuclear charge.
Read More: The Electronic Configuration of First 30 Elements
Ques 10: Elements of which of the following parts exhibit the property of decreasing atomic size with increasing atomic number.
- d−block
- f−block
- Radioactive series
- High atomic masses
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Ans. (B) f-block
Explanation: A trait of elements in the f-block is the decrease in atomic size with the increase in atomic number. Both lanthanoid and actinoid contractions refer to it. This is brought on by the f subshell's electrons' inadequate shielding.
Ques 11: Sort S, O, and Se according to their increasing electron affinities
- Se < S < O
- O < Se < S
- S < O < Se
- S < Se < O
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Ans. (B) O < Se < S
Explanation: A group's electron affinity declines as its atomic number rises. Se, O, and S are all group 16 elements. Thus, the expected order of their increasing electron affinities would be O>S>Se. However, this is not the observed case as the oxygen atom is extremely small. So, oxygen cannot hold a negative charge in such a small space. Therefore, the electron affinity of oxygen is the lowest in the group.
Ques 12. Which order best depicts the oxides' progressively less acidic nature?
- Li2O > BeO > B2O3 > CO2 > N2O3
- N2O3 > CO2 > B2O3 > BeO > Li2O
- CO2 > N2O3 > B2O3 > BeO > Li2O
- B2O3 > CO2 > N2O3 > Li2O > BeO
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Ans. (B) N2O3 > CO2 > B2O32> BeO > Li2O
Explanation: The typical oxides of elements become more acidic as you move from left to right in a period as their electronegativity rises.
Ques 13. Which of the following oxides has the characteristics of an amphoteric?
- SnO2
- CO2
- SiO2
- CaO
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Ans. (a) SnO2
Explanation: SiO2 is slightly acidic, CaO is basic, and CO2 is acidic. SnO2 is amorphous.
Read More: Classification of Oxides
Ques 14: Elements that are considered to be representative elements are those that belong to
- p and d–Block
- s and d–Block
- s and p–Block
- s and f–Block
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Ans. (C) s and p–Block
Explanation: The term "representative elements" refers to substances with complete inner shells but incomplete outer shells, i.e., substances with fewer than 8 electrons in the outermost shell. Except for inert gas, the s and p block elements are referred to as representative elements.
Ques 15. The element next to F on Pauling's electronegativity scale is
- N
- Cl
- O
- Ne
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Ans. (C) O
Explanation: The ability of an atom in a molecule to draw electrons toward it is known as electronegativity, according to Pauling. When we examine the periodic table's trend, we can observe that while electronegativity increases between periods, it drops as we move down the groups. Pauling estimated the differences in electronegativity between the atoms in a covalent bond based on the bond energies and assigned the most electronegative element, fluorine, a value of 4, and other elements were calculated concerning that value. So, on Pauling's scale, oxygen is the element following fluorine.
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