NCERT Solutions for Class 11 Chemistry Chapter 4: Chemical Bonding and Molecular Structure

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NCERT Solutions for Class 11 Chemistry Chapter 4 Chemical Bonding and Molecular Structure is explained in detail in this article. Some of the important topics in Chemical bonding and Molecular structure includes:

  1. Bond Enthalpy
  2. Covalent Bond
  3. Ionic bond
  4. Nuclear bond
  5. Complex bonding
  6. Hybridisation
  7. Lewis' dot structure
  8. Molecular Orbital Theory
  9. Valence Bond Theory
  10. Chemical Bonding and Molecular Structure

Expected no of questions: 2 to 4 questions of total 7 marks

Download PDF: NCERT Solutions for Class 11 Chemistry Chapter 4 pdf


NCERT Solutions for Class 11 Chemistry Chapter 4

NCERT Solutions for Class 11 Chemistry Chapter 4 is given below.

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Class 11 Chemistry Chapter 4 Chemical Bonding and Molecular Structure – Important Topics

Chemical bonding exists between molecules of the same or different elements. It also exists between the subatomic particles. Some of the different types of bonding are:

  • Ionic/ Electrovalent Bond: This bond is established by the exchange of oppositely charged ion commonly taking place in a metal and non metal (eg: Sodium and Chlorine).
  • Covalent Bond: Covalent bonding is where electrons are shared between the participating molecules.
  • Nuclear Bond: This is the bonding force that keeps the protons and neutrons together inside the nucleon.

Lattice Enthalpy of an ionic solid is defined as the energy required to completely separate one mole of a solid ionic compound into gaseous constituent ions.

Types of bonds can be characterized based on the bond parameters. Some of the bond parameters are:

  • Bond length
  • Bond angle
  • Bond enthalpy
  • Bond order
  • Resonance structures

Hybridisation is the process of intermixing the orbitals of slightly different energies to redistribute their energies resulting in the formation of new sets of orbitals of equivalent energies and shapes. The various hybridisation are:

  • sp
  • sp2
  • sp3
  • sp3d
  • sp3d2

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CBSE CLASS XII Related Questions

  • 1.
    Complete each synthesis by giving missing starting material, reagent, or products:
    synthesis by giving missing starting material, reagent


      • 2.
        Hoffmann Bromamide degradation reaction is given by:

          • ArNO$_2$
          • ArNH$_2$
          • ArCONH$_2$
          • ArCH$_2$NH$_2$

        • 3.
          Calculate emf of the following cell at 25°C: \[ \text{Zn}(s) \, | \, \text{Zn}^{2+} (0.1M) \, || \, \text{Cd}^{2+} (0.01M) \, | \, \text{Cd}(s) \] Given: \[ E^\circ_{\text{Zn}^{2+}/\text{Zn}} = -0.40 \, \text{V}, \quad E^\circ_{\text{Cd}^{2+}/\text{Cd}} = -0.76 \, \text{V}. \]


            • 4.
              Complete the following reactions by writing the structural formulae of ‘A’ and ‘B’:
              (i) CH$_3$CH=CH$_2$ + HBr $\xrightarrow{\text{Peroxide}}$ ‘A’ $\xrightarrow{KOH}$ ‘B’
              (ii) CH$_3$CH$_2$CHCl + alc. KOH $\xrightarrow{\Delta}$ ‘A’ $\xrightarrow{\text{H}_2\text{O}}$ ‘B’ (Main product)


                • 5.
                  Assertion (A): n-Butyl chloride has higher boiling point than n-Butyl bromide.
                  Reason (R): C—Cl bond is more polar than C—Br bond.

                    • Both Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of Assertion (A).
                    • Both Assertion (A) and Reason (R) are true, but Reason (R) is not the correct explanation of Assertion (A).
                    • Assertion (A) is true, but Reason (R) is false.
                    • Assertion (A) is false, but Reason (R) is true.

                  • 6.
                    Assertion (A): Electrolysis of aqueous NaCl gives H$_2$ at cathode and Cl$_2$ at anode.
                    Reason (R): Chlorine has higher oxidation potential than H$_2$O.

                      • Both Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of Assertion (A).
                      • Both Assertion (A) and Reason (R) are true, but Reason (R) is not the correct explanation of Assertion (A).
                      • Assertion (A) is true, but Reason (R) is false.
                      • Assertion (A) is false, but Reason (R) is true.
                    CBSE CLASS XII Previous Year Papers

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