COPPER (I) CHLORIDE FORMULA: Derivation & Properties

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Jasmine Grover

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Copper (I) Chloride is a chemical substance that is often white in colour and can appear to be green due to the presence of oxidized impurities. It is also popularly known as cuprous chloride. This compound is somewhat soluble in water but is completely soluble in concentrated hydrochloric acid (HCl). The substance is often used as an agrochemical. Cuprous Chloride was first made by Robert Boyle around the mid-seventeenth century. He prepared it by using mercury (II) Chloride and copper metal. Other names for Copper (I) Chloride are Copper monochloride, Dicopper dichloride.

Key Takeaways: Copper (I) Chloride, oxidation state, Copper, Chlorine, Hard-Soft Acid-Base Concept


What is Copper (I) Chloride?

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Copper (I) Chloride is a chemical substance in which copper appears in the oxidation state +1. Some general properties of Copper (I) Chloride are as follows:

Chemical Formula CuCl
Other Names Cuprous Chloride
Appearance Powder, White with slight green
Molecular Weight 98.996 g/mol

Copper (I) Chloride

Copper (I) Chloride

Also Read: Copper Chloride Formula


Copper (I) Chloride Formula and its Derivation

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The formula of Copper (I) Chloride is CuCl. Derivation of the formula of Copper (I) Chloride is as follows:

2Cu + Cl2 → 2CuCl

Structural Formula: Copper (I) Chloride has a zincblende crystal structure. By heating this at 408°C, the structure changes to a hexagonal shape. It is also a lewis acid-containing empty orbitals, capable of accepting electron pairs from lewis base.

Structural Formula (Figure): Cl—Cu

Also read: Thermal conductivity of Copper


Properties of Copper (I) Chloride

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Copper (I) Chloride has various properties and features, some of which are noted here as follows:

  1. Copper (I) Chloride is insoluble (or soluble to an extent at times) but it is soluble in aqueous solutions which have the appropriate donor molecules present.
  2. Copper (I) Chloride is a lewis acid, and is soft in the HSAB (Hard-Soft Acid-Base) and so it forms stable complexes with soft lewis bases like triphenylphosphine.

Some other important properties of Copper (I) Chloride are as follows:

Density 4.14 g/cm3
Solubility in water 0.047 g/L or 0.00062 g/100ml
Boiling Point 1,490°C
Melting Point 423°C

Things to remember

  1. Copper (I) Chloride is called Cuprous Chloride.
  2. It is the inorganic and lower part of Copper. The copper appears in a +1 oxidation state.
  3. Cuprous Chloride is mostly insoluble in water but is soluble in aqueous solutions.
  4. It is a Soft type in the HSAB (Hard-soft Acid-Base) concept.
  5. Other names for Copper (I) Chloride are Cuprous Chloride, Copper monochloride, Dicopper dichloride.

Solved Questions

Ques: Derive the formula for Copper (I) Chloride. (5 Marks)

Ans: Firstly, Write the symbol for copper and chlorine (chloride)

Copper - Cu, Chlorine - Cl

Next, we write the formula using the symbols

CuCl- Cu1+ Cl1-

Since +1 and -1 = 0

Therefore, we get CuCl (Copper (I) Chloride).

Ques: What is the difference between Copper (I) Chloride and Copper (II) Chloride? (5 Marks)

Ans: The difference between Copper (I) Chloride and Copper (II) Chloride is as follows:

COPPER (I) CHLORIDE COPPER (II) CHLORIDE
Copper (II) Chloride is white with a slight green colour due to oxidized impurities. Copper (II) Chloride is a yellow-brown solid (anhydrous), blue-green solid (dihydrate) in colour.
Another name for Copper (I) Chloride is Cuprous Chloride. Another name for Copper (II) Chloride is Cupric Chloride.
Metal is found in a +1 oxidation state. Metal is found in a +2 oxidation state.
The chemical formula for Copper (I) Chloride is CuCl The chemical formula for Copper (II) Chloride is CuCl2
STRUCTURE FORMULA: Cu–Cl STRUCTURE FORMULA: COPPER (II) CHLORIDE

Ques: What are some of the important uses of Copper (I) Chloride? (3 Marks)

Ans: Copper (I) Chloride is used for various uses which are as follows:

  1. It is often used as a catalyst in organic reactions.
  2. It also acts as a decolourising agent for substances like petroleum.
  3. It is used in industries like copper manufacturing, pigments, etc.
  4. It also works as a denigrating agent for substances like cellulose.
  5. Petroleum industry often uses the substance for a process called oil-sweetening.
  6. Copper (I) Chloride is also used in pyrotechnics as a colouring agent for the colour blue and/ or green.

Ques: How and when was Cooper (I) Chloride first prepared. Also, mention the equation which helps to prepare Cooper (I) Chloride. (5 Marks)

Ans: Copper (I) Chloride was first prepared by Robert Boyle in the mid-seventeenth century. He prepared Copper (I) Chloride using Mercury (II) Chloride (HgCl2) and copper metals. The following equation represents the reaction:

HgCl2 + 2Cu → 2CuCl + Hg

Copper (I) Chloride is usually prepared by a direct combining of copper metals and chlorine at 450- 900°C. The equation for the same is:

2 Cu + CL2 → 2CuCl

Another way of preparing Copper (I) Chloride is reducing Copper (II) Chloride (CuCl2) with sulfur dioxide (SO2). The equation for the same is:

2CuCl2 + SO2 + H2O → 2CuCl + H2SO4 + 2HCl

Ques: Why is Copper (I) Chloride covalent (CuCl) and why is Potassium Chloride (NaCl) ionic? (5 Marks)

Ans: To understand why CuCl is covalent and NaCl covalent. We need to first understand the effect called polarization. Polarization refers to the effect on cation and anions wherein, when a cation approaches an anion, it leads to more electron clouds from the cation getting attracted to the anion, leading to distortion.

With an increase in polarization, there is an increase in the concentration of electrons between atoms, leading towards a covalent character rather than ionic. And when there are two cations with equal dimensions the one with a pseudo noble gas structure has more polarizing power. In the case of CuCl and NaCl, CuCl has a pseudo noble gas structure and so it is more covalent.

Ques: Differentiate between Copper (I) Chloride and Copper (I) Sulfate. (5 Marks)

Ans: The differences between Copper (I) Chloride and Copper (I) Sulfate:

COPPER (I) CHLORIDE COPPER (I) SULFATE
The formula for Copper (I) Chloride is CuCl. The formula for Copper (I) Sulfate is Cu2SO4.
It is mostly white in colour with slight green. In its appearance, it is a white solid.
Copper (I) Chloride is prepared by various methods, one of which is by reducing Copper (II) Chloride with sulfur dioxide. The equation for this is: 2CuCl2 + SO2 + 2H2O → CuCl + H2SO4 + HCl Copper (I) Sulfate is often prepared by reaction between Copper metal and sulfuric acid at 200°C. The equation for it is: 2Cu + 2H2SO4 → Cu2SO4 + SO2 + 2H2O

Ques: What is the difference between Copper (I) Chloride and Copper (I) Oxide? (3 Marks)

Ans: Difference between Copper (I) Chloride and Copper (I) Oxide are as follows:

COPPER (I) CHLORIDE COPPER (I) OXIDE
Copper (I) Chloride is an inorganic chloride of copper, in which the metal has + 1 oxidation state. Copper (I) Oxide is an inorganic compound and is also one of the principal oxides of copper.
The formula of Copper (I) Chloride is CuCl. The formula of Copper(I) Oxide is Cu2O.
One of the methods of producing Copper (I) Chloride is by direct combination of Copper metals and chlorine at 450-900?. The equation for it is: 2Cu + CL2 → 2CuCl Method for producing Copper (I) Oxide is by oxidizing the copper metal. The equation for it is: 4Cu + O2 → 2Cu2O

Ques: What is the difference between Copper (I) Chloride and Copper (I) Acetylide? (3 Marks)

Ans: The differences between Copper (I) Chloride and Cooper (I) Acetylide are as follows:

COPPER (I) CHLORIDE COPPER (I) ACETYLIDE
Copper (I) Chloride, also called Cuprous Chloride, is a lower chloride of copper. It is mostly white with slight green (sometimes even off white). Copper (I) Acetylide, also called Cuprous Acetylide is a chemical compound. In terms of appearance, it is a reddish colour solid.
The formula for Copper (I) Chloride is CuCl. The formula for Copper (I) Acetylide is C2Cu2.
Copper (I) Chloride is used in pyrotechnics and is often also used as an agrochemical. Copper (I) Acetylide is often used in organic chemistry.

Ques: What is the difference between ammoniacal cuprous chloride and cuprous chloride? (3 Marks)

Ans: The difference between Ammoniacal Cuprous Chloride and Cuprous Chloride are as follows:

AMMONIACAL CUPROUS CHLORIDE CUPROUS CHLORIDE
The formula for Ammoniacal Cuprous Chloride is Cl4CuH8N2 . The formula of Cuprous Chloride is CuCl.
It is obtained by dissolving cuprous chloride in water and ammonia. It is obtained by combining copper metals with chlorine at 450-900°C.

The structural formula of Ammoniacal Cuprous Chloride:

The structural formula of Ammoniacal Cuprous Chloride

Structural formula of Cuprous Chloride: Cu–Cl

Ques: What is ammoniacal cuprous chloride? Explain how Copper acetylide is formed with Ammoniacal Cuprous Chloride with formula? (3 Marks)

Ans: Ammoniacal cuprous chloride is in simple words the solution of Cuprous Chloride in ammonia. Its formula is Cl4CuH8N2 . Copper acetylide is prepared by treating acetylene with CuCl and Ammonia. The equation for the same is

C2H2 (g) + 2CuCl (s) → Cu2C2 + HCl (g)

The precipitation thus formed from the reaction is a red solid.

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