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The Quantum Theory of Light was introduced by Albert Einstein. It explains that light travels in bundles of energy. Each bundle has been termed as a photon. Every photon contains a quantity of energy. This is equivalent to the product of the frequency of vibration of that photon and Planck's constant.
Keyterms: Light, Quantum theory, Energy, Photon, Planck's constant, Wavelength, Frequency of light, Electromagnetic spectrum, Speed of lightWave Theory of Light
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Diffraction and Interference are different kinds of behaviours of waves. As per James Clerk Maxwell, light is an electromagnetic wave. It travels at the speed of light through space. As per the below equation, the frequency of light is relevant to its wavelength:
V = c / λ
v=frequency, c=speed of light, and λ=wavelength
The regions of the electromagnetic spectrum have been given names based on their frequency range:
Electromagnetic Sprectrum
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Particle Behaviour of Light
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The concept stating light consists of particles called photons is backed by a well-known experiment — Photoelectric Effect.
Photoelectric Effect
A key feature of this experiment is that the electron is emitted by the metal with a certain kind of kinetic energy. A wave is related to its amplitude or intensity. For example, a bigger wave in the ocean is associated with a higher range of energy. Similarly, as the light gets brighter, some electrons are emitted. Yet, the kinetic energy remains the same.
Every metal holds a frequency, i.e., ν0. No electrons are emitted lower than this. It indicates that the kinetic energy equals the light frequency times a constant. This is known as Planck’s Constant by the symbol h.
h = 6.63 × 10-34 J · s ← Planck’s Constant
The equation for the kinetic energy of an emitted electron is:
KE = hv – hv0
where KE is the Kinetic energy of the emitted electron, h=6.63 x 10-34 J . s is Plank’s constant v is the frequency of the light, and v0 is the threshold frequency of the metal,
Also, since E = hv, the equation can also be written as
KE = E – Φ
where E is the energy of the light and Φ is the binding energy of the electron in the metal.
When the picture of light comes in sequential packages called photons, every photon must have sufficient energy to emit a single electron. As a result, the energy of a single photon is provided by,
Ephoton = h ν
Therefore, keeping all the phenomenons together, it can be stated that light is a particle containing wave properties.
Planck’s Quantum Theory of Light
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According to Planck’s Quantum Theory,
Energy emitted or absorbed is not continious, but is in the form of packets called quanta. In terms of light it is called a photon.
Each photon carries an energy which is directly proportional to the frequency of wavelenght i.e. E depends upon v (nu).
Or,
E=hv (where v is frequency)
Value of h =6.634 x 10-34Jsec
Energy associated with no of packets is given by:
E=nhv (where n is an integral multiple)
Planck determined that these were merely a subset of the radiation absorption and emission processes. They have nothing to do with the radiation's physical existence. Albert Einstein revised Planck's theory in 1905 to fully comprehend the photoelectric effect. He believed that if a light source was focused on specific materials, it might eject electrons from the material. Planck's theory led Einstein to the conclusion that light originates in discrete quanta of energy, or photons.
Quantum Theory: Wave-Particle Duality of Light
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According to quantum theory, matter and light are made up of minute particles. These particles have wave-like characteristics. Light is made up of particles called photons, and the matter is made up of particles called protons, electrons, and neutrons.
Wave-Particle Duality
Corpuscular Theory of Light
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The corpuscular theory of light was introduced by Sir Isaac Newton. As per the theory, the light emitted by luminous objects is made up of tiny particles of matter. These particles are called corpuscles. When this corpuscle makes contact with a surface, each particle reflects back. According to the theory, the velocity of light varies with the density of the medium. Corpuscular theory of light explains the three commonly-known concepts: reflection, refraction, and rectilinear light propagation.
Things to Remember
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- The photoelectrons' kinetic energy is not affected by the intensity of the light that causes the photoelectric effect.
- The highest kinetic energy of photoelectrons grows as light frequency increases.
- Light has the properties of both a particle and a wave. Light flows as waves from one point to the next. But, at the locations where it is emitted or absorbed, it follows the boundary conditions of a particle carrying energy ω, momentum k, and angular momentum.
- Planck proposed that light energy is proportional to frequency, and the constant that connects them is known as Planck's constant (h). His research contributed to Albert Einstein's discovery that light exists in discrete quanta of energy known as photons.
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Sample Questions
Ques. What is the wavelength of a photon that has energy of 5.25 x 10-19J? (3 Marks)
Ans. The wavelength and energy are related by the formula ΔE=hc / λ,
where h is Planck's constant (= 6.626 x 10-34 Js), c is the speed of light (3.00 x 108 m/s) and λ is the wavelength in meters.
The wavelength can then be calculated by rearranging the above formula as follows:
λ = hc / E (Energy of Photon)
= 3.79 x 10-7 Joules
Ques. With what energy will the fastest photoelectrons be emitted from a surface whose threshold wavelength is 600 nm, when the surface is illuminated by 400 nm light? (3 Marks)
Ans. We know, E=E0+1/2 mv2
We know, E=hc / λ0
=(6.626 x 10-34 J/s) x
= 3.31 x 10-19J
E=hc / λ
=(6.626 x 10-34 J/s) x
= 4.97 x 10-19J
Or E= 1.66 x 10-19J
Ques. Is light made of particles or waves? (3 Marks)
Ans. Light exhibits the behavior of both a particle and a wave. The Transactional Interpretation (TI) shows us that light moves from place to place as waves, but at locations where it is emitted or absorbed it obeys the boundary conditions of a particle carrying energy ω, momentum k, and angular momentum.
One might say that light travels as a wave but takes off and lands as a particle. It is usually convenient to think of low energy photons, e.g., radio transmissions, as waves, and high energy photons like X-rays and gamma rays as particles. In the TI the wavelike behavior is present in the offer and confirmation waves, and the particle-like behavior is present in the completed transactions.
Ques. What if Planck’s constant was zero? (3 Marks)
Ans. Setting to zero is a way of taking the classical limit of quantum mechanics: the uncertainty principle goes away, and in that limit, quantum mechanics becomes more or less equivalent to Newtonian mechanics.
However, Planck’s treatment of black body radiation suggests that a universe in which Planck’s constant was zero would be very different than ours because hot objects would rapidly radiate away all their energy as high-frequency electromagnetic radiation (the ultraviolet catastrophe), matter would be extremely cold, and the universe would be dominated by light.
Ques. What is the meaning of the angular frequency ω and wave number k of waves? (3 Marks)
Ans. Light waves have a characteristic frequency f indicating how many times per second the electric field of the light wave oscillates. The angular frequency ω is just the same characteristic expressed in radians of phase per second instead of oscillations per second, so ω = 2π f.
Light waves also have a characteristic wavelength λ as they move through space, which is the spatial distance between one electric-field maximum and the next. The wavenumber k is a way of looking at the reciprocal of that characteristic, so that k = 2π/λ.
The speed of light c is related to these quantities as c = f λ = ω/k. When we deal with particle waves, for example using the de Broglie wavelength, we also characterize them in terms of ω and k.
Ques. Explain photoelectric emission based on the quantum model of light and derive the equation hv= 1/2mv2+hv0, where symbols used have their usual meanings. (5 Marks)
Ans. The Quantum Theory of Radiations by Max Planck can explain the photoelectric effect very well. Max Planck says that light is made of bundles of energy known as photons, energy of each photon being equal to hv,v being the frequency of the light.
So, when a photon of frequency being equal to the threshold frequency of the metal strikes the metal surface, it imparts its whole energy to an electron and hence helps the electron to overcome the forces of attraction from the nucleus of the atom. In this way, an electron is ejected out of a metal surface when a photon strikes it.
If the frequency of the photon is less than v0 (threshold frequency), then no photoelectric effect is observed.
But if v>vo then some of its energy (which is equal to the ionization energy) is consumed in ejecting the electron from the metal and the remaining is used to impart some kinetic energy to the ejected electron.
hv=Φ+ 12mv2
Here, Φ is the ionization energy, v is the velocity imparted to the ejected electron, m is the mass of the electron.
As Φ=hvo
∴ hv=1/2mv2+hvo
Ques. According to quantum theory, a photon of electromagnetic radiation of frequency ν has energy E=hν where h is Planck's constant. According to the theory of relativity, a particle of mass m has equivalent energy E=mc2, where c is the speed of light. Thus, a photon can be treated as a particle having effective mass m=hvc2. If a flash of light is sent horizontally in earth’s gravitational field, then photons while traveling a horizontal distance d would fall through a distance given by: (6 Marks)
(a) gd2/2c2
(b) h/mc
(c) mcd2/h
(d) Zero
Ans. A photon is an elementary particle that is a carrier of electromagnetic fields or radiation. They are massless particles in the sense that their mass is zero at zero momentum. They always move at the speed of light c in free space and are the basic units of all mass. This property is also known as the invariant mass and remains independent of overall momentum.
We are given that the energy possessed by a photon is given as E=hν.
But from the mass-energy equivalence principle which states that a body in motion possesses relativistic mass that can be derived from its total energy divided by the speed of light squared, we see that energy possessed by a photon in motion can be quantified as:
E=mc2
Equating the two energy equations we get:
⇒hν=mc2⇒m=hv/c2
Let the photons fall through a distance s when a horizontal flash of light is sent through the earth’s gravitational field. The photons follow the kinematics of a projectile motion.
The photons travel with a horizontal velocity of c but have no vertical velocity associated with their motion.
Therefore, ux=c and uy=0
If the horizontal distance travelled by a photon following this trajectory is dx=d, then the time it takes to travel this distance is given by:
t=dx/ux=dc
Therefore, the distance through which the photon would fall vertically downwards in this time can be given by the kinematic equation of motion:
hy=uyt+1/2gt2
⇒s=0+1/2gt2
s=1/2g.(d/c)2=gd2 / 2c2
Therefore, the correct option would be A
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