What truly distinguishes universities such as DU, JNU, and BHU is their brand value and large alumni base. It's as if they've created a brand, particularly for social science courses. A degree from it is valuable in and of itself. Second, while faculty may be similar in some ways, exposure at DU is unparalleled. You will learn a lot.
MSU Baroda is a great university with a vibrant past and a strong alumni base, but in the current scenario, good colleges of DU stand out. But, yes, you must work hard and take the initiative to learn and gain knowledge wherever you study because, in the end, it is the knowledge you acquire that counts.