Class 12 Chemistry Chapter 2 Electrochemistry carries 68 problems in the NCERT Exemplar across five question types, more than the textbook exercise. It pushes Nernst equation, conductivity, electrolysis, and battery cells past CBSE level. This page hosts the 2026-27 Exemplar PDF, the question-type map, and the JEE / NEET mapping.

14 pages | 68 problems | 5 question types · Class 12 Chemistry Chapter 2, 2026-27 NCERT Exemplar
  • CBSE Weightage: 4-6 marks (one short answer plus one numerical)
  • JEE Main Weightage: 4-5% (2-3 questions per paper)
  • NEET Weightage: 2-3 questions per year

Download the full Electrochemistry Exemplar PDF below, with the question-type map, difficulty notes, and JEE / NEET mapping.

Curated by subject experts, mapped to the 2026-27 NCERT, and checked against five years of CBSE, JEE Main, and NEET papers.

Also Check:

Electrochemistry Exemplar Book PDF - Class 12 Chemistry

Electrochemistry Exemplar: MCQ, VSA, SA, LA Counts and Marks

The 68 problems span five types, shown below with counts and marks.

Question TypeQuestion NumbersCountTypical Marks
MCQ-I (single correct)Q1 – Q17171 each
MCQ-II (multiple correct)Q18 – Q27102 each
Short Answer (SA)Q28 – Q49222–3 each
Matching TypeQ50 – Q5562–4 each
Assertion & ReasonQ56 – Q65101 each
Long Answer (LA)Q66 – Q6835 each

Note: Short Answer and MCQ-II together carry 32 problems, almost half the Exemplar, so give them the most practice time.

Electrochemistry Class 12 Chemistry Explained

Source: Magnet Brains on YouTube

What's Inside the Electrochemistry Exemplar PDF

The 14-page PDF (pages 33-46 of NCERT Exemplar Problems Chemistry Class 12) includes:

  • 5 sections covering MCQ-I, MCQ-II, Short Answer, Matching, Assertion-Reason, and Long Answer.
  • Electrode potential data tables inside MCQs (Q8, Q55), so you read values from a block, not recall.
  • Galvanic-cell diagrams in the Long Answer set (Fig. 3.1-3.3) on polarity and electron flow.
  • Answer key at chapter end for every MCQ, MCQ-II, SA, Matching, and Assertion-Reason problem.
Concept: The Exemplar prints E° data inside the question stem, so Q8 to Q12 need reading and ranking, not recall.
Faraday's laws of electrolysis quote card with formula, first law, second law and example

How will Collegedunia's Exemplar Book PDF Help You with Electrochemistry?

The Exemplar Book PDF is the highest-yield HOTS resource for this chapter.

  • Searchable PDF: Jump to any question type in two clicks.
  • 2026-27 Alignment: Every dropped-from-textbook topic still in the Exemplar is flagged below.
  • JEE / NEET Mapping: The 15-20 problems mirrored in recent JEE Main and NEET papers are tabled below.
  • Expert Verification: Each question is tagged to its NCERT section and checked against the official E° table.

Electrochemistry Exemplar vs NCERT Textbook: Difficulty Comparison

The Exemplar is harder than the textbook: it twists each standard setup by adding one reasoning step.

ConceptNCERT TextbookExemplar Twist
Standard electrode potentialLook up E° for a single half-cellRank four species by reducing power from an E° data block (Q8-Q12)
Nernst equationCompute Ecell at given ion concentrationsMatch the E vs log[Mg2+] graph to one of four sketches (Q2)
Kohlrausch's lawFind Λ°m for a weak electrolyteExpress Λ°m(H2O) from HCl, NaOH, NaCl conductivities (Q22)
ElectrolysisCompute mass deposited from Q = ItPredict anode and cathode products for CuSO4 with Pt vs Cu electrodes (Q23, Q24)
Galvanic vs Electrolytic cellIdentify which is whichCouple a 2V cell to a 1.1V cell and identify which acts as electrolytic (Q66)

A student who can solve every textbook example still loses 4-6 marks on the Exemplar without separate practice.

Electrochemistry Old Syllabus vs 2026-27: What's Kept in the Exemplar

NCERT updated the textbook in 2023 but did not revise the Exemplar, so a few dropped sub-topics still appear.

Watch Out: The Exemplar still has Lechlanche cell and corrosion mechanism questions (Q52, Q54). The 2026-27 syllabus trims corrosion, so treat these as JEE-only, not CBSE board, practice.
  • Testable in 2026-27 boards: Nernst equation, conductivity and molar conductivity, Kohlrausch's law, electrolysis, EMF and Gibbs energy, fuel cells, lead storage battery, dry cell.
  • Exemplar-only / JEE-only: Lechlanche cell, mercury cell details, corrosion of iron mechanism.

Detailed kept-trimmed-removed table: Electrochemistry Class 12 Chemistry NCERT Book PDF

Types of commercial batteries - dry cell, mercury, lead-acid, Ni-Cd, hydrogen fuel cell and solar cell

Why the NCERT Exemplar Matters for JEE / NEET Electrochemistry Prep

Electrochemistry is a high-yield JEE / NEET chapter, and the Exemplar is the only NCERT resource pitched at entrance level.

  • Nernst equation numericals (Q2, Q46, Q64) mirror JEE Main 2024-2025 Ecell questions.
  • Conductivity on dilution (Q41, Q49, Q58, Q59) is a recurring NEET assertion-reason stem.
  • Electrolysis product prediction (Q23, Q24, Q34, Q39, Q42) appears in JEE Main most years, usually CuSO4 / Pt vs Cu.
  • Galvanic-cell representation (Q33, Q67) is a 4-marker on CBSE and JEE Main.
Quick Tip: Do all 27 MCQs (Q1-Q27), then the 10 Assertion-Reason (Q56-Q65). Those 37 cover 90% of the JEE Main / NEET pattern.

Electrochemistry Top 5 Formulae for Quick Exemplar Recall

These five cover Q2, Q20, Q22, Q25, Q46, Q49 and most Long Answers. The full sheet with units lives on the Formula Sheet.

QuantityFormula
Nernst equation (general)Ecell = E°cell − (0.059 / n) log Q
EMF and Gibbs energyΔrG° = −nFE°cell
Equilibrium constant and EMFlog Kc = (nE°cell) / 0.059
Conductivity and resistanceκ = (1/R) × (l/A) = G* / R
Molar conductivityΛm = κ / c (or κ × 1000 / c when c is in mol L−1)

Full master table: Electrochemistry Class 12 Chemistry Formula Sheet

Electrochemistry Exemplar Problems Mapped to JEE Main and NEET

Many of the 68 problems reappear in recent JEE Main and NEET papers with only number swaps. The 10 highest-impact picks:

Exemplar QTypeConceptMirrored in
Q2MCQ-INernst equation graph for Mg electrodeJEE Main 2024 Jan, Shift 1
Q8–Q12MCQ-I clusterRanking from E° data blockNEET 2023, NEET 2025
Q22MCQ-IIΛ°m(H2O) by Kohlrausch combinationJEE Main 2025 Apr, Shift 2
Q23, Q24MCQ-IIElectrolysis of CuSO4 with Pt vs Cu electrodesJEE Main 2024 Apr, Shift 1
Q41SAStrong vs weak electrolyte on dilutionNEET 2024
Q46SANernst equation for Daniell cellCBSE Board 2025
Q48SALead storage battery dischargeCBSE Board 2024, JEE Main 2023
Q56–Q60Assertion-ReasonConductivity, mercury cell, dilution effectsNEET 2022, NEET 2025
Q66LAGalvanic vs electrolytic when coupledCBSE Board 2023
Q67LAZn / Ag galvanic cell, electron flow, equilibriumCBSE Board 2024, NEET 2023

This 10-problem set covers roughly 7 of the 12 Electrochemistry marks across CBSE, JEE Main, and NEET 2025.

Electrochemistry Class 12: PYQ Snapshot for CBSE, JEE Main and NEET (2026 → 2021)

The top recurring sub-topics are Nernst numericals, electrolysis-product prediction, and conductivity on dilution. The full PYQ map lives on the NCERT Solutions page.

YearCBSE BoardJEE MainNEET
2026-Conductivity from cell constant (2 Qs)Pending (exam rescheduled)
2025Nernst equation (3 marks)Kohlrausch's law (1 Q)Electrolysis prediction (2 Qs)
2024Lead storage battery (3 marks)Electrolysis of CuSO4 (1 Q)Standard electrode potential ranking (1 Q)
2023Galvanic cell representation (5 marks)Nernst equation (1 Q)Mercury cell & primary batteries (1 Q)
2022Conductivity on dilution (2 marks)ΔG and EMF (1 Q)Fuel cell efficiency (1 Q)
2021EMF and equilibrium constant (3 marks)--

Full year-wise PYQ map: Electrochemistry Class 12 Chemistry NCERT Solutions

Student Feedback

In a Collegedunia poll of 900 Class 12 students, 78% said the Electrochemistry Exemplar felt harder than the textbook, mainly the Nernst-graph and E° ranking problems.

Other Resources for Electrochemistry Class 12 Chemistry

NCERT Exemplar Book PDF for Class 12 Chemistry: All Chapters

The table links every chapter's Exemplar Book PDF in the 2026-27 NCERT sequence.

Electrochemistry Class 12 Chemistry Exemplar Book PDF FAQs

Ques. Where can I download the Electrochemistry Class 12 Chemistry Exemplar Book PDF?

Ans. You can download the Electrochemistry Class 12 Chemistry NCERT Exemplar Book PDF directly from this page. Both the Normal and HD versions are available, and both are free.

Ques. How many problems does the Class 12 Chemistry Chapter 2 Electrochemistry Exemplar contain?

Ans. The Electrochemistry Exemplar has 68 problems spread across five question types: 17 MCQ-I, 10 MCQ-II, 22 Short Answer, 6 Matching, 10 Assertion-Reason, and 3 Long Answer. The full breakdown is in the question-type table on this page.

Ques. Is the Electrochemistry Exemplar aligned with the 2026-27 NCERT?

Ans. The NCERT Exemplar was not formally revised when the textbook was updated, so it still carries a few sub-topics (Lechlanche cell, corrosion mechanism) that are no longer tested on CBSE Boards. These problems remain useful for JEE Main practice. The kept-vs-trimmed list is in the "Old Syllabus vs 2026-27" section above.

Ques. How many pages is the Class 12th Chemistry Electrochemistry Exemplar Book PDF?

Ans. The Electrochemistry NCERT Exemplar PDF runs 14 pages (page 33 to page 46 of NCERT Exemplar Problems Chemistry Class 12) and covers MCQ-I, MCQ-II, Short Answer, Matching, Assertion-Reason, and Long Answer sets along with the answer key.

Ques. Which Electrochemistry Exemplar problems are most useful for JEE Main and NEET?

Ans. The high-yield set is Q2 (Nernst graph), Q8-Q12 (E° ranking), Q22 (Kohlrausch), Q23-Q24 (electrolysis products), Q41 (dilution), and Q46-Q48 (Daniell cell, lead storage). These ten mirror JEE Main 2023-2025 and NEET 2022-2025 patterns.

Ques. How is the Exemplar different from the NCERT textbook for Electrochemistry?

Ans. The textbook exercise tests single-step recall (compute Ecell, find mass deposited). The Exemplar adds one extra reasoning step on each setup, for example asking which of four sketches matches a Nernst E vs log[Mg2+] curve, or asking what happens when a 2V cell is coupled to a 1.1V cell. The "Exemplar vs NCERT Textbook" comparison table on this page lists 5 such twists.

Ques. Are the Exemplar answers given inside the PDF?

Ans. Yes. NCERT prints the answer key for all MCQ-I, MCQ-II, Short Answer, Matching, and Assertion-Reason problems at the end of the chapter (pages 44–46 of the Exemplar). Long Answer hints are also provided. For step-by-step worked solutions, use the Collegedunia Electrochemistry NCERT Exemplar Solutions page linked above.