Class 12 Chemistry Chapter 1 Solutions is one of the highest-weighted units of the Physical Chemistry block, opening Class 12 with colligative properties, Raoult's Law, and concentration arithmetic that recurs across Electrochemistry and Chemical Kinetics. This handwritten notebook PDF runs 21 pages with hand-drawn van't Hoff plots, ink-coded definition boxes, and a night-before-exam recall card.

21 pages · 14 hand-drawn diagrams · 9 colour-coded formula boxes · Class 12 Chemistry Chapter 1, 2026-27 NCERT
  • CBSE Weightage: 6 to 8 marks (long answer plus a numerical)
  • JEE Main Weightage: 3 to 4% (1 to 2 questions per shift on molality, Raoult, and van't Hoff factor)
  • NEET Weightage: 2 to 3 questions per year, mostly from osmotic pressure and depression of freezing point
Chapter 1 Solutions Handwritten Notes PDF

The handwritten notebook below opens with the solution-types table, walks through every concentration unit, and finishes with the abnormal molar mass card that tops most NEET MCQs from this chapter.

These handwritten notes are prepared by Collegedunia subject mentors, mapped to the 2026-27 NCERT print, and cross-checked against the last five years of CBSE Board, JEE Main, and NEET papers on Solutions.

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Solutions Handwritten Notes - Class 12 Chemistry

Solutions Handwritten Notes: Complete Diagram List for Class 12 Chemistry

The notebook contains 14 hand-sketched diagrams that the reader can copy onto rough paper during revision. The table below maps every figure to its page so a reader hunting one specific concept can jump straight to the right spread.

PageDiagramWhat It Shows
3Solid / Liquid / Gas mixing matrixThe nine solute-solvent combinations with one labelled real-life example each
5Mass percent and ppm strip chartSide-by-side concentration units with the SI base each carries
7Henry's Law plot of p vs xStraight line with slope KH and the deep-sea diver call-out
9Raoult's Law p-x diagramIdeal binary mixture with both partial vapour pressures and the total line
11Positive deviation curve (ethanol + acetone)Total pressure bows ABOVE the ideal line, with the H-bond breaking annotation
12Negative deviation curve (chloroform + acetone)Total pressure bows BELOW the ideal line, with the new H-bond formation note
13Minimum and maximum boiling azeotrope sketchesBoiling point vs composition with the constant-composition vertical drop
14Vapour-pressure lowering barHow a non-volatile solute reduces solvent vapour pressure linearly with mole fraction
15Elevation of boiling point thermogramSolvent vs solution curves on T-vs-vapour-pressure axes with ΔTb labelled
16Depression of freezing point thermogramMirror of the boiling-point sketch with ΔTf at the freezing point
17Osmosis cell schematicSemipermeable membrane with arrows showing net solvent flow and the π column
18Reverse osmosis desalination cartoonThe seawater → potable water flow with the pressure piston labelled
19Van't Hoff factor (i) table sketchAssociation vs dissociation cases with worked i-values for KCl, benzoic acid, and acetic acid
20Last-day mind mapOne-page concept tree linking concentration → vapour pressure → colligative properties → abnormal i
Quick Tip: Copy the Henry's Law sketch and the osmosis-cell schematic on the back of your answer sheet during revision; CBSE has asked one labelled diagram from this chapter in every Board paper since 2022.
Cycle diagram of the dissolution process showing energy balance

Solutions Video Walkthrough

Source: Magnet Brains on YouTube

Topics Covered in Class 12 Chemistry Chapter 1 Solutions Handwritten Notes

The handwritten notebook PDF maps every concept in the 2026-27 NCERT Chapter 1 onto its own ink-coded page. Concentration units (mass percent, ppm, mole fraction, molarity, molality) sit in a single side-by-side definition table for instant recall. Henry's law is drawn with a deep-sea-diver call-out; Raoult's law with both ideal and deviation curves. The colligative-property block carries hand-sketched thermograms for elevation in boiling point ( Δ Tb = Kb m i ) and depression in freezing point ( Δ Tf = Kf m i ), the relative lowering of vapour pressure bar diagram, and an osmotic pressure semipermeable-membrane cell. Real-world applications include reverse osmosis desalination, antifreeze in radiators, and salt-on-icy-roads. The notebook closes with the van't Hoff factor stick-figure for dissociation (NaCl, KCl, K2SO4) and association (benzoic acid dimer in benzene), and a one-page abnormal molar mass recall card.

Solutions Class 12 Chapter 1 NCERT Exercise-Wise Snapshot

The Solutions chapter packs roughly 41 exercise questions plus 14 intext examples. The brief table below shows how the questions split across the major sub-topics. The full exercise-by-exercise count with sub-topic tagging lives on the dedicated NCERT Solutions page.

Sub-TopicNCERT QsTypical CBSE Marks
Concentration Units (molarity, molality, mole fraction, ppm)72 to 3
Henry's Law and Solubility42
Raoult's Law and Vapour Pressure of Binary Mixtures93 to 5
Ideal / Non-Ideal Solutions and Azeotropes32 to 3
Colligative Properties (ΔTb, ΔTf, π)133 to 5
Abnormal Molar Mass and Van't Hoff Factor52 to 3

Full exercise-by-exercise count: Solutions Class 12 Chemistry NCERT Solutions

How will Collegedunia's Handwritten Notes Help You Crack Solutions?

The notebook is built to compress a 36-page NCERT chapter into a 21-page revision-friendly stack you can finish in two sittings.

  • Hand-Sketched Visual Anchors: Every key graph, p vs x curves, T vs vapour-pressure thermograms, osmosis cell, is drawn freehand so the reader can redraw it from memory in under 90 seconds.
  • Colour-Coded Box Legend: Orange for definitions, blue for formulas, yellow for numerical traps, red for common errors. The legend stays consistent across every chapter so revision flows.
  • 2026-27 NCERT Alignment: Every page is matched to the current 2026-27 syllabus print, with the molality-based formulas highlighted because CBSE has dropped molarity-based colligative-property questions in the new edition.
  • Concept-Flavoured Mnemonics: The notebook teaches you to remember the four colligative properties as the VBFO stack (Vapour-pressure lowering, Boiling-point elevation, Freezing-point depression, Osmotic pressure) so you never blank in MCQs.
VBFO mnemonic for the four colligative properties of solutions

Solutions Handwritten Notes Concept-Flavoured Mnemonics

Five mnemonics that the notebook uses repeatedly; memorise these once and you can recover most MCQ-style facts from this chapter without re-reading.

Remember -- VBFO: Vapour-pressure lowering → Boiling-point elevation → Freezing-point depression → Osmotic pressure. The four colligative properties in the exact order NCERT introduces them.
Remember -- Henry vs Raoult: Henry's constant KH goes UP when gas solubility goes DOWN. Hot water holds less oxygen because warming a solution raises KH, the inverse of solubility.
Remember -- Deviation direction: Positive deviation means solute-solvent attractions are WEAKER than the original pure-component bonds (think ethanol + acetone breaking H-bonds). Negative deviation means new attractions form (chloroform + acetone create a fresh H-bond).
Remember -- i, the van't Hoff factor: i > 1 means dissociation (electrolytes like NaCl, KCl, BaCl2). i < 1 means association (carboxylic acids in benzene). i = 1 means a non-electrolyte. Sketch the three cases as a stick figure splitting, combining, or staying still.
Remember -- Mass per cent vs molality: Mass per cent changes with temperature only when the solution is reported by volume (m/V). Molality (mol of solute per kg of solvent) is temperature-INDEPENDENT, which is why CBSE prefers it in numericals.

Solutions Handwritten Notes: Color Legend for the Notebook

The notebook uses four ink colours consistently. Knowing the legend lets you skim a 21-page PDF in eight minutes during last-day revision.

ColourBox TypeWhat's Inside
OrangeDefinition boxNCERT one-line definitions: solution, solute, solvent, mole fraction, molarity, molality
BlueFormula boxEvery working equation with units. p = KH · x , Δ Tb = Kb m i , π = CRT , etc.
YellowMCQ-trap calloutThe 7 facts CBSE / NEET re-use as MCQ distractors: ideal solution ΔH = 0, azeotrope can't be separated by fractional distillation, etc.
RedCommon-mistake boxMost students mis-write the colligative-property formulas; the red box shows the correct form right next to the wrong one

Solutions Top 6 Formulae for Class 12 Chemistry Quick Recall

These six formulas account for nearly every numerical CBSE and NEET have asked from this chapter since 2021. Treat them as the minimum to memorise; the dimensional check and "when to use which" decision tree live on the full Formula Sheet.

QuantityFormula
Molarity (M) M = nsoluteVsolution (L)
Molality (m) m = nsoluteWsolvent (kg)
Henry's Law p = KH · x
Raoult's Law (volatile-volatile) ptotal = pA0 xA + pB0 xB
Colligative properties (general) Δ Tb = Kb m i, Δ Tf = Kf m i, π = i C R T
Van't Hoff factor i = observed colligative propertycalculated colligative property (no dissociation)

Full master table: Solutions Class 12 Chemistry Formula Sheet

Solutions: Last 24-Hour Revision Card for Class 12 Chemistry

The single page below is what you should scan the night before the Board exam. Skip the derivations; the marks come from formula recall plus one labelled diagram.

  1. Concentration definitions: molarity (T-dependent), molality (T-independent), mole fraction (sums to 1), ppm (mass / mass × 106). CBSE asks one definition every year.
  2. Henry's Law and one application: p = KH x; deep-sea divers breathe helium because helium has higher KH than nitrogen at depth.
  3. Raoult's Law for two volatiles: ptotal = p°AxA + p°BxB, and yA = pA/ptotal for the vapour-phase mole fraction.
  4. Two deviation graphs and their cause: positive (weaker new attractions) and negative (stronger new attractions). Sketch from memory.
  5. Four colligative properties with formulas: Δp, ΔTb, ΔTf, π, all proportional to molality and to the van't Hoff factor.
  6. Van't Hoff factor cases: i > 1 dissociation, i < 1 association, i = 1 non-electrolyte. Remember benzoic acid in benzene has i = 0.5 (dimer).
  7. One numerical setup: compute molality from mass per cent or mole fraction in under 90 seconds; this is the most-asked numerical type.
Watch Out: Students routinely apply ΔTf = Kf · m without the van't Hoff factor i for electrolyte solutes. CBSE deducts 1 mark every time. Always multiply by i for NaCl, KCl, BaCl2, and similar dissociating solutes.

Solutions Class 12 Chemistry Self-Assessment Quick Quiz

Five MCQs in the style CBSE Board and NEET have asked since 2022. Tap each question to reveal the answer.

Q1. The van't Hoff factor (i) of a 0.1 m K4[Fe(CN)6] solution (assume complete dissociation) is:

(a) 2   (b) 3   (c) 4   (d) 5

Answer: (d) 5 -- K4[Fe(CN)6] dissociates into 4 K+ and 1 [Fe(CN)6]4−, so 5 particles total.

Q2. Which of the following pairs forms a maximum-boiling azeotrope?

(a) Ethanol + water   (b) Hexane + heptane   (c) Nitric acid + water   (d) Methanol + acetone

Answer: (c) Nitric acid + water -- the negative deviation pair forms a maximum-boiling azeotrope at 68% HNO3.

Q3. The molality of a 10% (w/w) aqueous NaOH solution is approximately:

(a) 2.78 m   (b) 2.50 m   (c) 0.25 m   (d) 1.39 m

Answer: (a) 2.78 m -- 10 g NaOH (0.25 mol) in 90 g water = 0.25 / 0.090 = 2.78 m.

Q4. For an ideal solution, ΔHmix and ΔVmix are:

(a) Both positive   (b) Both negative   (c) Both zero   (d) Cannot be predicted

Answer: (c) Both zero -- ideal solutions show no enthalpy change and no volume change on mixing.

Q5. Reverse osmosis is most commonly used in:

(a) Hydrogen production   (b) Desalination of seawater   (c) Refining sugar   (d) Distillation of alcohol

Answer: (b) Desalination of seawater -- pressure greater than the seawater's osmotic pressure forces water through a semipermeable membrane.

Class 12th Chemistry Chapter 1 Solutions PYQ Snapshot (2026 to 2021)

Three highest-recurring question stems from the last six papers. The complete year-wise CBSE / JEE Main / NEET table with marks tagging lives on the dedicated NCERT Solutions page.

TopicAsked inTypical Marks
Calculate ΔTf or ΔTb for a dissociating solute (include i)CBSE 2025, 2023, NEET 2025, 2024, 20223
Define ideal vs non-ideal solution; sketch deviation curvesCBSE 2024, 2022, JEE Main 2025, 20232 to 3
Osmotic pressure calculation and definition of isotonic solutionCBSE 2025, NEET 2025, 20232 to 3

Full year-wise PYQ map: Solutions Class 12 Chemistry NCERT Solutions

Best Way to Use These Solutions Handwritten Notes

Treat the notebook as a two-pass revision tool rather than a textbook substitute. The first read is for visual encoding; the second is for formula and trap consolidation.

  • Pass 1 (45 minutes): Flip through the 14 hand-drawn diagrams and the colour-coded legend without reading prose. The point is to imprint the visual layout so you can later "see" where every formula sits.
  • Pass 2 (60 minutes): Read the blue formula boxes plus every yellow MCQ-trap. Cover the right side of the page and recall the formula from the variable name.
  • Pass 3 (last 24 hours): Skim only the last-day revision card (page 20) and re-sketch the deviation curves and the osmosis cell from memory.
  • Active recall: After Pass 2, solve the five MCQs above without referring back. If you score below 4, return to Pass 2; if 4 to 5, you are exam-ready on this chapter.

Related Links:

Solutions Weightage Compared Across Class 12 Chemistry Chapters

The visual below maps the typical CBSE Board mark distribution across all 10 chapters of the 2026-27 NCERT Chemistry book, averaged over the last five years.

Ch 1 Solutions
7 marks
Ch 2 Electrochemistry
6 marks
Ch 3 Chemical Kinetics
6 marks
Ch 4 The d- and f-Block Elements
5 marks
Ch 5 Coordination Compounds
7 marks
Ch 6 Haloalkanes and Haloarenes
4 marks
Ch 7 Alcohols, Phenols and Ethers
5 marks
Ch 8 Aldehydes, Ketones and Carboxylic Acids
6 marks
Ch 9 Amines
5 marks
Ch 10 Biomolecules
4 marks

Solutions ties with Coordination Compounds at the top of the bar chart at 7 marks, so a strong revision pass on this chapter alone secures a tangible chunk of the Class 12 Chemistry paper.

More Solutions Chemistry Class 12 Resources

NCERT Handwritten Notes for Class 12 Chemistry: All Chapters

Use the table below to jump to any other Class 12 Chemistry chapter's handwritten notebook PDF. The same colour-coded box legend and last-day revision card runs through every chapter.

Solutions Class 12 Chemistry Handwritten Notes FAQs

Ques. Where can I download Solutions Class 12 Chemistry Handwritten Notes PDF?

Ans. You can download the Solutions Class 12 Chemistry Handwritten Notes PDF directly from this page. Both the Normal and HD versions are available, and both are free.

Ques. Are these handwritten notes aligned with the 2026-27 NCERT?

Ans. Yes. The notebook reflects the current 2026-27 syllabus for Class 12 Chemistry. The new NCERT edition keeps Solutions intact as Chapter 1 and emphasises molality-based colligative-property numericals over the older molarity-based variants.

Ques. How many pages is the Class 12th Chemistry Solutions Handwritten Notes PDF?

Ans. The handwritten notes PDF runs 21 pages and covers concentration units, Henry's Law, Raoult's Law, ideal and non-ideal behaviour, every colligative property with formulas, and the van't Hoff factor with worked cases.

Ques. Are these notes enough to score full marks in CBSE Boards Chapter 1?

Ans. The handwritten notes cover every CBSE-relevant topic and include the last-24-hour revision card. For full-marks performance, pair the notebook with the NCERT exercise solutions and the Exemplar problems so you have practiced every typical 3-mark numerical at least once.

Ques. Do these handwritten notes help with JEE Main and NEET Solutions questions?

Ans. Yes. JEE Main and NEET draw 1 to 3 questions per year from this chapter, and the yellow MCQ-trap boxes inside the notebook are calibrated against the last five years of these entrance papers, in particular the abnormal molar mass and van't Hoff factor stems.

Ques. What's the difference between Collegedunia's Handwritten Notes and the regular Notes for Class 12 Chemistry Chapter 1?

Ans. The regular Notes carry the deep concept walkthrough with detailed explanations of every sub-topic. The Handwritten Notes compress the same content into a faster, more visual revision tool with hand-drawn diagrams, colour-coded boxes, and a 24-hour pre-exam recall card. Use Notes for first read, Handwritten Notes for second and third passes.

Ques. Which sub-topic of Solutions carries the most weight in CBSE Board exams?

Ans. Colligative properties (boiling-point elevation, freezing-point depression, osmotic pressure) and the van't Hoff factor together account for roughly 4 to 5 of the 6 to 8 marks CBSE assigns to this chapter, and they have been asked in some form in every Board paper since 2022.

Ques. What is the easiest way to remember the four colligative properties?

Ans. Use the VBFO mnemonic on page 20 of the notebook: Vapour-pressure lowering, Boiling-point elevation, Freezing-point depression, Osmotic pressure. All four depend only on the number of solute particles and pick up a factor of i (the van't Hoff factor) for electrolytes. The colour-coded formula box on page 14 carries the four equations side by side.

Ques. How does the handwritten notebook explain positive and negative deviation from Raoult's law?

Ans. Pages 11 and 12 carry two hand-sketched p-vs-x curves. Positive deviation (ethanol + acetone) bows above the ideal Raoult line because acetone breaks the H-bond network and weakens A-B forces; it forms a minimum-boiling azeotrope. Negative deviation (chloroform + acetone) bows below the ideal line because chloroform forms a new H-bond with acetone's carbonyl; it forms a maximum-boiling azeotrope. The annotation arrows on each diagram make the H-bond logic visible.

Ques. Why do we use molality instead of molarity in colligative-property numericals?

Ans. Molality is moles of solute per kilogram of solvent, so it is independent of temperature. Molarity is moles of solute per litre of solution; the volume changes with temperature, so molarity drifts. CBSE numericals on Δ Tb , Δ Tf , and relative lowering of vapour pressure always use molality. The yellow MCQ-trap box on page 14 of the notebook captures this.

Ques. How does the notebook handle the van't Hoff factor for dissociation and association?

Ans. Page 19 carries a three-case stick-figure sketch. For dissociation (NaCl, K2SO4, CaCl2) the figure splits, i > 1 . For association (benzoic acid dimer in benzene, acetic acid in benzene) the figure combines, i < 1 . For a non-electrolyte (glucose, urea), the figure stays still, i = 1 . The formulas α = (i-1)/(n-1) for dissociation and α = (1-i)/(1 - 1/n) for association sit in a blue formula box right next to the sketch.

Ques. What is osmotic pressure and how does reverse osmosis work?

Ans. Osmotic pressure π = i C R T is the pressure that must be applied to the more-concentrated side of a semipermeable membrane to stop net solvent flow. Reverse osmosis applies a pressure greater than π on the concentrated side (e.g. sea water at roughly 30 atm), forcing solvent the other way and leaving solute behind. The osmosis-cell schematic on page 17 of the notebook and the desalination cartoon on page 18 walk through the setup with labelled arrows.