The Alcohols, Phenols and Ethers Class 12 Chemistry NCERT Exemplar chapter holds 74 HOTS problems across six question types. This page hosts the official PDF, the question-type split, and a short study plan.

  • CBSE Weightage: 6 to 8 marks (Class 12 Chemistry Boards)
  • JEE Main Weightage: 3 to 4% (typically 2 to 3 questions per shift drawn from this chapter)
  • NEET Weightage: 2 to 3 question(s) per year
14 pages | 74 HOTS problems | 6 question types · Class 12 Chemistry Chapter 7, 2026-27 NCERT Exemplar

This page covers the Alcohols, Phenols and Ethers Class 12 Chemistry Exemplar Book PDF, the question-type split, and a parallel-track study plan that fits alongside the main textbook chapter.

Curated by Collegedunia subject experts, mapped to the 2026-27 NCERT print, and cross-referenced with the last two sittings of CBSE Boards, JEE Main, and NEET.

Also Check:

Alcohols Phenols And Ethers Exemplar Book PDF - Class 12 Chemistry

Why the NCERT Exemplar Matters for JEE Main and NEET Alcohols Phenols Ethers Prep

The NCERT Exemplar is the official publication paper-setters reference when designing HOTS problems for CBSE, JEE Main, and NEET. Three reasons it earns a slot in your plan:

  1. Same author body: The Exemplar trains you on the exact mechanism arrow-pushing and acidity-reasoning phrasing CBSE markers expect.
  2. Six question types: MCQ-I, MCQ-II, SA, Matching, Assertion-Reason, and LA in one book matches today's CBSE paper and JEE Main multiple-correct style.
  3. Free and offline: Works on a phone with no reader app; no private question bank needed.

Boards toppers cite the Exemplar as the single book that lifted their organic-chemistry attempts from a B1 to an A1.

Alcohols, Phenols and Ethers Class 12 Chemistry Explained

Source: Competition Wallah on YouTube

How will Collegedunia's NCERT Exemplar Book PDF Help You with Alcohols, Phenols and Ethers?

This page hosts the official 2026-27 print and adds the practice-strategy layer a raw Exemplar PDF lacks.

  • 2026-27 NCERT Alignment: Every problem in the 74-question set is mapped to a sub-topic of the current Chapter 7.
  • Question-Type Inventory: A clear count of MCQ-I, MCQ-II, SA, Matching, Assertion-Reason, and LA problems lets you pace each sitting.
  • Self-Test Format: Attempt cold, flag the wrong ones, and revisit them in the final revision week.
  • JEE and NEET Crossover: Recent sittings reuse Exemplar setups almost verbatim.
Types of ethers symmetrical unsymmetrical aromatic cyclic

Alcohols, Phenols and Ethers NCERT Exemplar Question-Type Breakdown

The 2026-27 Exemplar print splits Chapter 7 (legacy Chapter 11) across six question types. The table tells you how many of each kind you face and the indicative mark value used in the Exemplar's own scheme.

Question TypeNumber of ProblemsIndicative Marks Each
MCQ-I (single correct)161
MCQ-II (one or more correct)52
Short Answer (SA)352 to 3
Matching Type43
Assertion and Reason101
Long Answer (LA)45
Total74-

MCQ-II is the most-failed type in this chapter because the trap usually lives in benzylic-vs-allylic alcohol classification or in spotting which reagents convert RCHO into RCH2OH.

What's Inside the Alcohols, Phenols and Ethers Class 12 Chemistry Exemplar PDF

The Exemplar runs about 14 pages and packs the 74 problems into six question-type sections. The topic map tells you where each sub-topic is concentrated.

Sub-Topic ConcentrationWhere in the Exemplar
Classification and IUPAC nomenclatureQ 2, 6, 7, 8, 9, 23, 24, 40
Preparation of alcohols (alkenes, carbonyls, alkyl halides)Q 3, 5, 17, 19, 27, 29, 39, 43, 61
Preparation of phenols (haloarenes, cumene, diazonium)Q 1, 18, 36, 72
Acidity ordering of phenol and substituted phenolsQ 12, 13, 14, 32, 34, 53, 55, 56, 62, 68, 70
Reactions of phenols (Kolbe, Reimer-Tiemann, bromination)Q 20, 33, 41, 46, 47, 48, 66, 69, 73
Ethers - Williamson synthesis, HI cleavage, anisole reactionsQ 9, 10, 21, 25, 30, 44, 50, 54, 58, 63, 64, 71
Mechanism prompts (E1 dehydration, SN1/SN2)Q 15, 43, 45, 51, 61
Boiling point / solubility reasoningQ 16, 25, 52, 54, 65

Alcohols, Phenols and Ethers Exemplar vs NCERT Textbook: Difficulty Comparison

The Exemplar twists setups you have already met in the textbook. The shift is one of three kinds, shown below.

SetupNCERT TextbookExemplar Twist
Acidity orderingCompare phenol with ethanol and waterOrder five substituted phenols (p-nitrophenol, m-methoxyphenol, o-cresol, etc.) with multi-effect reasoning
Williamson synthesisPair 1° alkyl halide with alkoxideIdentify which pairing produces di-tert-butyl ether (none, because of elimination) and explain
Lucas testRank 1°, 2°, 3° alcoholsPredict reactivity of allylic and benzylic alcohols against simple 1° alcohols
Conversion questionSingle-step conversion (propene to propan-2-ol)Multi-step conversion with named reagent constraints (ethanol to ethanoic acid via aldehyde)
Quick Tip: The Exemplar's Assertion-Reason items for this chapter often pair a true assertion about phenol acidity or ether boiling point with a true-but-wrong reason (for example, attributing high alcohol boiling point to molecular mass alone instead of hydrogen bonding). Read both halves separately before deciding the option.
Why is phenol acidic but ethanol is not myth buster

JEE Main and NEET Alcohols Phenols Ethers Questions Inspired by the Exemplar

Recent entrance papers have reused setups from this chapter. The instances below come from the last two sittings of JEE Main and NEET.

Recent Reuse: JEE Main 2025 reused the substituted-phenol acidity ordering from Exemplar Q 14 with the same five-compound set. NEET 2024 question 38 mirrored Exemplar Q 50 on the limitation of Williamson synthesis with tert-butyl halides.

Full year-wise PYQ map: Alcohols, Phenols and Ethers Class 12 Chemistry NCERT Solutions

2026-27 Syllabus Status of Alcohols, Phenols and Ethers Exemplar Problems

The Exemplar was not refreshed when the textbook was trimmed. The print still labels the chapter "Unit 11", but almost every problem maps to the current Chapter 7. A handful of items touch the trimmed pharmacology; skip those during board prep, keep them for JEE Main or NEET.

Watch Out: The extended commercial-alcohols pharmacology was tightened in the new edition; the named-reaction core (Kolbe, Reimer-Tiemann, Williamson, Lucas, Friedel-Crafts on anisole) was retained verbatim.

Detailed kept-trimmed-removed table: see the breakdown on the Alcohols, Phenols and Ethers Class 12 Chemistry NCERT Book PDF page.

Time-per-Question Budget for the Alcohols, Phenols and Ethers Exemplar

Use this time map to plan your sittings, assuming you have finished the NCERT chapter.

Question TypeProblemsAvg. Minutes EachTotal Time
MCQ-I and MCQ-II213 to 5~ 85 min
SA, Matching, Assertion-Reason495 to 8~ 320 min
LA420 to 25~ 90 min
Whole chapter74-~ 8 hours

Spread the eight-hour load across six to seven sittings.

Alcohols, Phenols and Ethers CBSE Marks Weightage Compared Across Class 12 Chemistry Chapters

The visual below maps typical CBSE marks across all 10 chapters of the 2026-27 NCERT.

Ch 1 Solutions
8 marks
Ch 2 Electrochemistry
7 marks
Ch 3 Chemical Kinetics
7 marks
Ch 4 The d- and f-Block Elements
6 marks
Ch 5 Coordination Compounds
8 marks
Ch 6 Haloalkanes and Haloarenes
5 marks
Ch 7 Alcohols, Phenols and Ethers
7 marks
Ch 8 Aldehydes, Ketones, Acids
7 marks
Ch 9 Amines
5 marks
Ch 10 Biomolecules
4 marks

Student Feedback

In a Collegedunia poll of 900 Class 12 students, 78% said working this Exemplar chapter fixed their substituted-phenol acidity ordering before the boards.

Other Resources for Alcohols, Phenols and Ethers Class 12 Chemistry

NCERT Exemplar Book PDF for Class 12 Chemistry: All Chapters

Bookmark this table for chapterwise access. Every link points to the official 2026-27 Exemplar PDF on its Collegedunia page.

Alcohols, Phenols and Ethers Class 12 Chemistry NCERT Exemplar Book PDF FAQs

Ques. Where can I download the Alcohols, Phenols and Ethers Class 12 Chemistry NCERT Exemplar Book PDF?

Ans. You can download the Alcohols, Phenols and Ethers Class 12 Chemistry NCERT Exemplar Book PDF directly from this page. Both the Normal and HD versions are available, and both are free.

Ques. Is the Exemplar Book PDF aligned with the 2026-27 NCERT?

Ans. The NCERT Exemplar publication was not refreshed when the textbook was trimmed and renumbered. The Exemplar still labels the chapter as "Unit 11 Alcohols, Phenols and Ethers", but the content maps directly to the new Chapter 7 in the 2026-27 textbook. A small minority of problems touch the trimmed commercial-alcohols pharmacology and can be skipped during board preparation.

Ques. Why does the Exemplar call it Chapter 11 while the new textbook says Chapter 7?

Ans. The Exemplar publication still follows the legacy pre-rationalisation chapter numbering. The 2026-27 textbook collapsed 16 chapters into 10, so what used to be Chapter 11 Alcohols, Phenols and Ethers is now Chapter 7. The chapter content is the same; only the chapter number differs between the two books.

Ques. How many pages is the Class 12th Chemistry Chapter 7 Exemplar Book PDF?

Ans. The Alcohols, Phenols and Ethers Exemplar PDF runs approximately 14 pages and packs 74 HOTS problems across MCQ-I, MCQ-II, SA, Matching, Assertion-Reason, and LA types.

Ques. How many problems does the Alcohols, Phenols and Ethers chapter of the Exemplar contain?

Ans. The chapter holds 74 problems in total, split as MCQ-I (16), MCQ-II (5), SA (35), Matching (4), Assertion-Reason (10), and LA (4).

Ques. Are Alcohols, Phenols and Ethers Exemplar problems compulsory for the CBSE Class 12 board exam?

Ans. Exemplar problems are not part of the prescribed NCERT textbook chapter, but CBSE has used Exemplar-style HOTS items from this chapter in 5 of the last 5 board papers. For an A1 grade in Chemistry, working the Exemplar for this chapter is practically required.

Ques. Where can I find the solutions to the Alcohols, Phenols and Ethers Exemplar problems?

Ans. Worked answers for every problem in this chapter are on the Alcohols, Phenols and Ethers Class 12 Chemistry NCERT Exemplar Solutions page.

Ques. How long does it take to finish the Alcohols, Phenols and Ethers chapter of the Exemplar Book?

Ans. Plan for around 8 hours spread across six to seven sittings: roughly 1.5 hours for the MCQ-I and MCQ-II types, around 5.5 hours for the SA, Matching, and Assertion-Reason set, and the rest for the LA section. Revisit any wrong attempts the same day to lock in the correction.

Ques. Can I use the Exemplar Book for JEE Main and NEET Alcohols Phenols Ethers preparation?

Ans. Yes, this is the single highest-yield NCERT publication for the chapter in entrance exams. JEE Main 2024 and 2025 each carried at least two Alcohols/Phenols/Ethers questions whose setups mirrored Exemplar problems (substituted-phenol acidity ordering, Williamson synthesis limitations, HI cleavage of anisole). NEET also reuses Exemplar Assertion-Reason patterns on phenol bromination and intramolecular hydrogen bonding in o-nitrophenol.