Class 12 Chemistry Chapter 1 Solutions packs nearly 60 graded problems in the official NCERT Exemplar, far more than the textbook's 41. The Collegedunia Exemplar PDF on this page mirrors that workload and adds JEE Main and NEET tagging.

11 pages · 58 graded problems · 5 question types · Class 12 Chemistry Chapter 1, 2026-27 NCERT
  • CBSE Weightage: 6 to 8 marks (one numerical plus one short-answer is the standard split)
  • JEE Main Weightage: 3 to 4% (one or two questions per shift on Raoult's law, colligative properties, or van't Hoff factor)
  • NEET Weightage: 2 to 3 questions per year, almost always on osmotic pressure, depression of freezing point, or abnormal molar mass

The Collegedunia NCERT Exemplar Book PDF on this page is curated by subject experts, mapped to the 2026-27 Class 12 Chemistry syllabus, and refined against the last five years of CBSE Board, JEE Main and NEET papers.

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Solutions Exemplar Book PDF - Class 12 Chemistry

Solutions Class 12 Chemistry NCERT Exemplar Question-Type Breakdown

The Solutions Exemplar is one of the most balanced sets in Class 12 Chemistry: every type from one-mark MCQ-I to five-mark Long-Answer appears, with a high share of numerical Short-Answer items.

Question TypeCountMarks eachTypical focus
MCQ-I (single correct)161Definitions, ideal vs non-ideal, sign of i, units of concentration
MCQ-II (multiple correct)52Henry's-law gases, azeotrope behaviour, positive-deviation pairs
Very Short Answer (VSA)101One-line distinctions, formula recall, single-step calculations
Short Answer (SA)202–3Numericals on molarity, molality, freezing-point depression, vapour-pressure lowering
Long Answer (LA)45Multi-part osmotic-pressure problems, abnormal molar mass with van't Hoff factor, derivation-style proofs
Matching / Assertion-Reason31–2Concept-pairing, dilute-solution assumptions

Around 60% of the marks come from Short-Answer numericals, so students fast at molality, mole-fraction and freezing-point depression lock in most of the score.

Solutions Class 12 Chemistry Explained

Source: Sourabh Raina on YouTube

What's Inside the Solutions Exemplar Book PDF

The Collegedunia Exemplar Book PDF is the official NCERT Exemplar chapter for Solutions, re-typeset with cleaner labels and one-line topic tags. The contents are:

  • Section-1.1 to Section-1.9 question mapping (so you can attempt only those questions whose topic you have just revised)
  • 16 MCQ-I + 5 MCQ-II + 10 VSA + 20 SA + 4 LA + 3 Match-the-Column / Assertion-Reason — 58 problems in total
  • Six topic-tags used throughout: Concentration units, Solubility & Henry's law, Vapour pressure & Raoult's law, Ideal vs non-ideal, Colligative properties, Abnormal molar mass & van't Hoff factor
  • Boxed formulae carried at the top of every two-page spread
  • JEE Main / NEET inspiration markers next to questions that have appeared in recent entrance papers
Concept: The Exemplar is not only numericals. About one-fifth are pure-concept items on the sign of ΔmixH, the type of deviation, or the value of i. Read the chapter before attempting.

How will Collegedunia's NCERT Exemplar Book PDF Help You with Solutions?

The Exemplar is a question paper, not a study book. The Collegedunia layered version does the orientation work for you:

  • 2026-27 NCERT Alignment: Every question is labelled with its rationalised textbook section, so deleted topics stay out of revision.
  • Difficulty Step-Up Markers: A one-to-three dot rating flags how far each problem sits above textbook level.
  • Expert Verification: Answers and significant figures are re-checked against the official NCERT key.
  • JEE / NEET Cross-References: Where a problem reappeared in JEE Main or NEET, the year is noted.
Reaction equation showing NaCl dissociation in water with van't Hoff factor explained

Solutions Exemplar vs NCERT Textbook: Difficulty Step-Up

The Exemplar lifts the standard NCERT setup by adding an extra unknown, a non-ideal twist, or a unit-conversion trap.

ConceptNCERT textbook askExemplar twist
Freezing-point depressionFind Tf given mass and KfFind Kf backwards, with an associating or dissociating solute requiring the van't Hoff factor
Raoult's law for two volatile liquidsTotal vapour pressure of an ideal mixturePredict whether the mixture is ideal, positive-deviation or negative-deviation; justify with intermolecular-force argument
Henry's lawCalculate solubility of a gas at given pressureCompare KH values across four gases at a fixed temperature and rank the solubilities, then explain the physical reason
Watch Out: In Exemplar LA problems, the colligative formula is only step one. Step two uses the result to identify the solute, so recall common molar masses (urea = 60, glucose = 180, sucrose = 342). A wrong identification costs two marks.

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Why the NCERT Exemplar Matters for JEE and NEET Solutions Prep

Solutions is one of the most reliably tested chapters in both JEE Main and NEET, and the Exemplar doubles as an entrance-prep workbook.

  • Three of the last five JEE Main January shifts carried a question that maps onto an Exemplar MCQ-II from this chapter.
  • NEET 2025 had two questions on osmotic pressure and freezing-point depression matching Exemplar LA-1 and SA-15.
  • The matching-column items train the azeotrope and Henry's-law recognition JEE Main now uses.
  • Working the LA pool builds the multi-step stamina NEET demands.

Solutions Exemplar Always-On: Old vs Rationalised Syllabus

The NCERT Exemplar Problems book was not re-published after the 2024 rationalisation, so for many chapters it still carries trimmed topics. Solutions is the lucky exception.

Remember: The rationalised 2026-27 textbook kept Solutions essentially intact; only the numbering changed (old Chapter 2 is now Chapter 1). So every Exemplar question here is still in syllabus, with no topic-skip filter needed. Removed chapters like "Solid State" and "Surface Chemistry" are not so lucky.

Detailed kept-trimmed-removed table: Solutions Class 12 Chemistry NCERT Book PDF

Myth-vs-fact panel about gas solubility decreasing with temperature

Solutions Exemplar JEE Main and NEET Question Mapping

The table below shows how often Solutions-chapter Exemplar problems have been adapted by recent JEE Main and NEET papers. The pattern is consistent: paper-setters lift the setup, change the numbers, and reuse the conceptual hook.

YearExamConcept liftedExemplar Q-type counterpart
2025JEE Main (Jan, Shift 1)Vapour-pressure lowering for non-volatile soluteSA-12 / SA-13
2025NEETOsmotic pressure with van't Hoff factorLA-2
2024JEE Main (April)Henry's-law constant rankingMCQ-II Q-3
2024NEETDepression in freezing point of an electrolyteSA-17
2023JEE MainPositive-deviation pair identificationMCQ-II Q-4
2022NEETMolarity-vs-molality temperature-dependence framingVSA-6

Every Exemplar attempt is therefore double duty: it tightens your board answer-writing and rehearses the exact concept that an entrance paper-setter is likely to reuse the same year.

Full year-wise PYQ map: Solutions Class 12 Chemistry NCERT Solutions

Solutions Weightage Compared Across Class 12 Chemistry Chapters

The visual below maps the typical CBSE Board marks distribution across all 10 chapters of the rationalised 2026-27 Class 12 Chemistry NCERT, averaged over the last five board papers. Solutions sits comfortably in the upper band alongside Coordination Compounds.

Ch 1 Solutions
7 marks
Ch 2 Electrochemistry
6 marks
Ch 3 Chemical Kinetics
6 marks
Ch 4 d- and f-Block Elements
5 marks
Ch 5 Coordination Compounds
7 marks
Ch 6 Haloalkanes and Haloarenes
4 marks
Ch 7 Alcohols, Phenols, Ethers
5 marks
Ch 8 Aldehydes, Ketones, Acids
6 marks
Ch 9 Amines
5 marks
Ch 10 Biomolecules
4 marks

Student Feedback

In a Collegedunia poll of 900 Class 12 students, 78% said the Solutions Exemplar's Short-Answer numericals were the fastest way to lock in board marks.

Other Resources for Solutions Class 12 Chemistry

NCERT Exemplar Book PDF for Class 12 Chemistry: All Chapters

The table below lists the Exemplar Book PDFs Collegedunia hosts for every chapter of the rationalised 2026-27 Class 12 Chemistry syllabus.

Solutions Class 12 Chemistry Exemplar Book PDF FAQs

Ques. Where can I download Solutions Class 12 Chemistry NCERT Exemplar Book PDF?

Ans. You can download the Solutions Class 12 Chemistry NCERT Exemplar Book PDF directly from this page. Both the Normal and HD versions are available, and both are free.

Ques. Is the Solutions Exemplar PDF aligned with the 2026-27 NCERT?

Ans. Yes. The Solutions chapter was retained almost intact in the new NCERT edition, so every Exemplar question for this chapter is still in syllabus. The only structural change is that Solutions is now Chapter 1 in the Class 12 Chemistry book (it was Chapter 2 in the old edition).

Ques. How many pages is the Class 12th Chemistry Solutions Exemplar Book PDF?

Ans. The Exemplar Book PDF for Solutions runs approximately 11 pages and carries 58 graded problems split across MCQ-I, MCQ-II, VSA, SA and LA, plus a small set of matching and assertion-reason items.

Ques. How many questions are in the Solutions chapter NCERT Exemplar?

Ans. The Solutions Exemplar contains 58 problems: 16 MCQ-I, 5 MCQ-II, 10 VSA, 20 SA, 4 LA, and 3 matching or assertion-reason items. Roughly 60% of the marks come from the Short-Answer numerical pool.

Ques. Is the NCERT Exemplar enough for JEE Main and NEET preparation for Solutions?

Ans. For the Solutions chapter, the Exemplar is unusually well-aligned with the entrance pattern. Three of the last five JEE Main shifts and the last two NEET papers have used setups that map directly onto Exemplar MCQ-II and LA items. The Exemplar is therefore a strong supplement to the NCERT textbook, though serious aspirants still pair it with a topic-tagged JEE archive.

Ques. What is the difference between the NCERT textbook problems and the NCERT Exemplar for Solutions?

Ans. The textbook problems usually test one concept per question (e.g. apply Raoult's law). The Exemplar adds a twist: an extra unknown, a non-ideal mixture, or a back-calculation step. Exemplar Long-Answer items also chain two formulas (e.g. find molar mass from freezing-point depression, then identify the organic solute).

Ques. Which topics in the Solutions Exemplar are most important for CBSE Board exams?

Ans. Three sub-topics dominate the CBSE pattern for this chapter: depression in freezing point, relative lowering of vapour pressure with Raoult's law, and osmotic pressure with van't Hoff factor for electrolytes. Exemplar SA-12 through SA-20 cover these exhaustively.